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All results from a given calculation for HOF (Hypofluorous acid)

using model chemistry: MP4=FULL/Sadlej_pVTZ

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes CS 1A'
Energy calculated at MP4=FULL/Sadlej_pVTZ
 hartrees
Energy at 0K-175.252944
Energy at 298.15K 
HF Energy-174.790540
Nuclear repulsion energy32.925215
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at MP4=FULL/Sadlej_pVTZ
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A' 3707 3707        
2 A' 1359 1359        
3 A' 853 853        

Unscaled Zero Point Vibrational Energy (zpe) 2959.4 cm-1
Scaled (by 1) Zero Point Vibrational Energy (zpe) 2959.4 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at MP4=FULL/Sadlej_pVTZ
ABC
19.01686 0.86684 0.82905

See section I.F.4 to change rotational constant units
Geometric Data calculated at MP4=FULL/Sadlej_pVTZ

Point Group is Cs

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
O1 0.054 0.725 0.000
H2 -0.919 0.842 0.000
F3 0.054 -0.738 0.000

Atom - Atom Distances (Å)
  O1 H2 F3
O10.97981.4633
H20.97981.8554
F31.46331.8554

picture of Hypofluorous acid state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
H2 O1 F3 96.833
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability