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	hartrees
Energy at 0K	-678.906165
Energy at 298.15K	-678.910139
HF Energy	-678.106731
Nuclear repulsion energy	273.667219

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A'	3310	3310	14.51
2	A'	1454	1454	70.35
3	A'	1202	1202	221.92
4	A'	941	941	185.68
5	A'	844	844	71.75
6	A'	562	562	92.25
7	A'	479	479	60.15
8	A'	377	377	44.76
9	A'	265	265	0.56
10	A"	3421	3421	5.13
11	A"	1044	1044	226.56
12	A"	843	843	1.42
13	A"	464	464	0.01
14	A"	373	373	19.30
15	A"	203	203	0.56

Atom	x (Å)	y (Å)	z (Å)
P1	-0.023	0.123	0.000
C2	-0.490	1.662	0.000
F3	1.463	-0.411	0.000
F4	-0.490	-0.695	1.243
F5	-0.490	-0.695	-1.243
H6	-0.522	2.197	-0.930
H7	-0.522	2.197	0.930

	P1	C2	F3	F4	F5	H6	H7
P1		1.6079	1.5792	1.5597	1.5597	2.3265	2.3265
C2	1.6079		2.8480	2.6647	2.6647	1.0736	1.0736
F3	1.5792	2.8480		2.3323	2.3323	3.4064	3.4064
F4	1.5597	2.6647	2.3323		2.4860	3.6176	2.9088
F5	1.5597	2.6647	2.3323	2.4860		2.9088	3.6176
H6	2.3265	1.0736	3.4064	3.6176	2.9088		1.8609
H7	2.3265	1.0736	3.4064	2.9088	3.6176	1.8609

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
P1	C2	H6	119.021	P1	C2	H7	119.021
C2	P1	F3	126.658	C2	P1	F4	114.532
C2	P1	F5	114.532	F3	P1	F4	95.975
F3	P1	F5	95.975	F4	P1	F5	105.676
H6	C2	H7	120.141

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)

using model chemistry: MP3=FULL/6-31G**

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF3CH2 (phosphorane, trifluoromethylene-)

using model chemistry: MP3=FULL/6-31G**

States and conformations

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)