Vibrational Frequencies calculated at M06-2X/6-31G**
| Mode Number |
Symmetry |
Frequency (cm-1) |
Scaled Frequency (cm-1) |
IR Intensities (km mol-1) |
Raman Act (Å4/u) |
Dep P |
Dep U |
| 1 |
A1' |
2016 |
1916 |
0.00 |
|
|
|
| 2 |
A2" |
715 |
680 |
205.17 |
|
|
|
| 3 |
E' |
2011 |
1911 |
247.06 |
|
|
|
| 3 |
E' |
2011 |
1911 |
247.84 |
|
|
|
| 4 |
E' |
775 |
737 |
158.67 |
|
|
|
| 4 |
E' |
775 |
737 |
158.65 |
|
|
|
Unscaled Zero Point Vibrational Energy (zpe) 4152.3 cm
-1
Scaled (by 0.9504) Zero Point Vibrational Energy (zpe) 3946.3 cm
-1
See section
III.C.1 List or set vibrational scaling factors
to change the scale factors used here.
See section
III.C.2
Calculate a vibrational scaling factor for a given set of molecules
to determine the least squares best scaling factor.
Charges, Dipole, Quadrupole and Polarizability
Charges from optimized geometry at M06-2X/6-31G**
Charges (e)
| Number |
Element |
Mulliken |
CHELPG |
AIM |
ESP |
| 1 |
Ga |
0.178 |
|
|
|
| 2 |
H |
-0.059 |
|
|
|
| 3 |
H |
-0.059 |
|
|
|
| 4 |
H |
-0.059 |
|
|
|
Electric dipole moments
Electric dipole components in Debye
(What's a Debye? See section
VII.A.3)
| |
x |
y |
z |
Total |
| |
0.000 |
0.000 |
0.000 |
0.000 |
| CHELPG |
|
|
|
|
| AIM |
|
|
|
|
| ESP |
|
|
|
|
Electric Quadrupole moment
Quadrupole components in D Å
| Primitive |
| | x | y | z |
| x |
-21.899 |
0.000 |
0.000 |
| y |
0.000 |
-21.899 |
0.000 |
| z |
0.000 |
0.000 |
-16.291 |
|
| Traceless |
| | x | y | z |
| x |
-2.804 |
0.000 |
0.000 |
| y |
0.000 |
-2.804 |
0.000 |
| z |
0.000 |
0.000 |
5.609 |
|
| Polar |
| 3z2-r2 | 11.218 |
| x2-y2 | 0.000 |
| xy | 0.000 |
| xz | 0.000 |
| yz | 0.000 |
|
Polarizabilities
Components of the polarizability tensor.
Units are
Å
3 (Angstrom cubed)
Change units.
| |
x |
y |
z |
| x |
4.480 |
0.000 |
0.000 |
| y |
0.000 |
4.477 |
0.000 |
| z |
0.000 |
0.000 |
3.111 |
<r2> (average value of r
2) Å
2
| <r2> |
20.010 |
| (<r2>)1/2 |
4.473 |