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	hartrees
Energy at 0K	-540.297777
Energy at 298.15K
HF Energy	-539.724787
Nuclear repulsion energy	106.056850

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁	847	807	137.56	7.50	0.32	0.48
2	A₁	355	338	10.61	1.39	0.66	0.80
3	B₂	822	783	202.19	6.41	0.75	0.86

Atom	y (Å)	z (Å)
P1	0.000	0.577
F2	1.219	-0.481
F3	-1.219	-0.481

	P1	F2	F3
P1		1.6148	1.6148
F2	1.6148		2.4390
F3	1.6148	2.4390

All results from a given calculation for PF₂ (Phosphorus difluoride)

using model chemistry: MP2=FULL/TZVP

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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HF vs MP2 Bad vib. Calc. vs exp. 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All results from a given calculation for PF2 (Phosphorus difluoride)

using model chemistry: MP2=FULL/TZVP

States and conformations

All results from a given calculation for PF₂ (Phosphorus difluoride)