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All results from a given calculation for CH4 (Methane)

using model chemistry: MP4/TZVP

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes TD 1A1
Energy calculated at MP4/TZVP
 hartrees
Energy at 0K-40.407571
Energy at 298.15K-40.410589
HF Energy-40.212219
Nuclear repulsion energy13.446328
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at MP4/TZVP
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A1 3054 2941        
2 E 1557 1499        
2 E 1557 1499        
3 T2 3180 3062        
3 T2 3180 3062        
3 T2 3180 3062        
4 T2 1369 1318        
4 T2 1369 1318        
4 T2 1369 1318        

Unscaled Zero Point Vibrational Energy (zpe) 9906.0 cm-1
Scaled (by 0.9629) Zero Point Vibrational Energy (zpe) 9538.5 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at MP4/TZVP
ABC
5.28272 5.28272 5.28272

See section I.F.4 to change rotational constant units
Geometric Data calculated at MP4/TZVP

Point Group is Td

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
C1 0.000 0.000 0.000
H2 0.629 0.629 0.629
H3 -0.629 -0.629 0.629
H4 -0.629 0.629 -0.629
H5 0.629 -0.629 -0.629

Atom - Atom Distances (Å)
  C1 H2 H3 H4 H5
C11.08971.08971.08971.0897
H21.08971.77941.77941.7794
H31.08971.77941.77941.7794
H41.08971.77941.77941.7794
H51.08971.77941.77941.7794

picture of Methane state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
H2 C1 H3 109.471 H2 C1 H4 109.471
H2 C1 H5 109.471 H3 C1 H4 109.471
H3 C1 H5 109.471 H4 C1 H5 109.471
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability