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All results from a given calculation for O3 (Ozone)

using model chemistry: B97D3/6-31+G**

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes C2V 1A1
Energy calculated at B97D3/6-31+G**
 hartrees
Energy at 0K-225.319588
Energy at 298.15K-225.320559
HF Energy-225.319588
Nuclear repulsion energy68.432387
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at B97D3/6-31+G**
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A1 1182 1162 0.03      
2 A1 704 692 5.19      
3 B2 1067 1049 208.44      

Unscaled Zero Point Vibrational Energy (zpe) 1476.7 cm-1
Scaled (by 0.9828) Zero Point Vibrational Energy (zpe) 1451.3 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at B97D3/6-31+G**
ABC
3.67331 0.43795 0.39130

See section I.F.4 to change rotational constant units
Geometric Data calculated at B97D3/6-31+G**

Point Group is C2v

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
O1 0.000 0.000 0.437
O2 0.000 1.097 -0.219
O3 0.000 -1.097 -0.219

Atom - Atom Distances (Å)
  O1 O2 O3
O11.27851.2785
O21.27852.1944
O31.27852.1944

picture of Ozone state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
O2 O1 O3 118.236
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability
Charges from optimized geometry at B97D3/6-31+G** Charges (e)
Number Element Mulliken CHELPG AIM ESP
1 O 0.239      
2 O -0.119      
3 O -0.119      


Electric dipole moments
Electric dipole components in Debye
(What's a Debye? See section VII.A.3)
  x y z Total
  0.000 0.000 0.637 0.637
CHELPG        
AIM        
ESP        


Electric Quadrupole moment
Quadrupole components in D Å
Primitive
 xyz
x -14.663 0.000 0.000
y 0.000 -17.254 0.000
z 0.000 0.000 -16.154
Traceless
 xyz
x 2.041 0.000 0.000
y 0.000 -1.846 0.000
z 0.000 0.000 -0.195
Polar
3z2-r2-0.390
x2-y22.591
xy0.000
xz0.000
yz0.000


Polarizabilities
Components of the polarizability tensor.
Units are Å3 (Angstrom cubed)
Change units.
  x y z
x 1.372 0.000 0.000
y 0.000 4.448 0.000
z 0.000 0.000 1.793


<r2> (average value of r2) Å2
<r2> 31.556
(<r2>)1/2 5.617