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	hartrees
Energy at 0K	-678.936953
Energy at 298.15K	-678.940816
HF Energy	-678.118757
Nuclear repulsion energy	271.367835

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A'	3280	3080	18.15
2	A'	1420	1334	57.14
3	A'	1161	1090	234.91
4	A'	881	827	190.80
5	A'	796	748	102.41
6	A'	536	503	80.77
7	A'	463	435	58.66
8	A'	362	340	36.44
9	A'	256	241	1.09
10	A"	3400	3194	11.58
11	A"	988	928	241.36
12	A"	830	779	0.29
13	A"	454	427	0.03
14	A"	357	335	17.86
15	A"	212	199	0.83

Atom	x (Å)	y (Å)	z (Å)
P1	-0.023	0.125	0.000
C2	-0.497	1.671	0.000
F3	1.478	-0.420	0.000
F4	-0.497	-0.697	1.255
F5	-0.497	-0.697	-1.255
H6	-0.509	2.204	-0.935
H7	-0.509	2.204	0.935

	P1	C2	F3	F4	F5	H6	H7
P1		1.6172	1.5963	1.5737	1.5737	2.3309	2.3309
C2	1.6172		2.8762	2.6800	2.6800	1.0765	1.0765
F3	1.5963	2.8762		2.3565	2.3565	3.4214	3.4214
F4	1.5737	2.6800	2.3565		2.5106	3.6350	2.9184
F5	1.5737	2.6800	2.3565	2.5106		2.9184	3.6350
H6	2.3309	1.0765	3.4214	3.6350	2.9184		1.8705
H7	2.3309	1.0765	3.4214	2.9184	3.6350	1.8705

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
P1	C2	H6	118.453	P1	C2	H7	118.453
C2	P1	F3	127.024	C2	P1	F4	114.252
C2	P1	F5	114.252	F3	P1	F4	96.038
F3	P1	F5	96.038	F4	P1	F5	105.823
H6	C2	H7	120.634

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)

using model chemistry: MP2=FULL/6-31+G**

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF3CH2 (phosphorane, trifluoromethylene-)

using model chemistry: MP2=FULL/6-31+G**

States and conformations

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)