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	hartrees
Energy at 0K	-540.778091
Energy at 298.15K
HF Energy	-540.622741
Nuclear repulsion energy	105.465759

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁	830	830	134.63	10.07	0.43	0.60
2	A₁	336	336	9.59	1.09	0.64	0.78
3	B₂	815	815	201.92	7.76	0.75	0.86

Atom	y (Å)	z (Å)
P1	0.000	0.578
F2	1.230	-0.481
F3	-1.230	-0.481

	P1	F2	F3
P1		1.6229	1.6229
F2	1.6229		2.4597
F3	1.6229	2.4597

All results from a given calculation for PF₂ (Phosphorus difluoride)

using model chemistry: B2PLYP=FULLultrafine/6-31+G**

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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HF vs MP2 Bad vib. Calc. vs exp. 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All results from a given calculation for PF2 (Phosphorus difluoride)

using model chemistry: B2PLYP=FULLultrafine/6-31+G**

States and conformations

All results from a given calculation for PF₂ (Phosphorus difluoride)