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	hartrees
Energy at 0K	-154.181168
Energy at 298.15K	-154.186005
HF Energy	-154.181168
Nuclear repulsion energy	76.783457

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A	3215	3178	10.90
2	A	3092	3057	14.86
3	A	3057	3022	23.36
4	A	3009	2974	50.01
5	A	2943	2909	63.16
6	A	1455	1438	18.66
7	A	1445	1429	5.83
8	A	1438	1422	7.93
9	A	1408	1392	1.41
10	A	1254	1240	137.44
11	A	1210	1196	18.01
12	A	1127	1114	1.43
13	A	1101	1088	5.20
14	A	939	928	33.28
15	A	541	535	62.25
16	A	419	414	4.29
17	A	295	292	6.21
18	A	164	162	2.92

Atom	x (Å)	y (Å)	z (Å)
O1	0.092	-0.548	-0.040
C2	-1.144	0.170	0.014
C3	1.208	0.230	0.068
H4	-1.945	-0.568	-0.130
H5	-1.263	0.666	0.995
H6	-1.191	0.930	-0.790
H7	2.137	-0.334	-0.021
H8	1.141	1.284	-0.227

	O1	C2	C3	H4	H5	H6	H7	H8
O1		1.4306	1.3639	2.0394	2.0931	2.0958	2.0559	2.1189
C2	1.4306		2.3528	1.0989	1.1055	1.1069	3.3194	2.5531
C3	1.3639	2.3528		3.2580	2.6747	2.6417	1.0905	1.0965
H4	2.0394	1.0989	3.2580		1.8035	1.8020	4.0900	3.6003
H5	2.0931	1.1055	2.6747	1.8035		1.8057	3.6868	2.7666
H6	2.0958	1.1069	2.6417	1.8020	1.8057		3.6416	2.4249
H7	2.0559	3.3194	1.0905	4.0900	3.6868	3.6416		1.9107
H8	2.1189	2.5531	1.0965	3.6003	2.7666	2.4249	1.9107

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
O1	C2	H4	106.726	O1	C2	H5	110.587
O1	C2	H6	110.722	O1	C3	H7	113.312
O1	C3	H8	118.502	C2	O1	C3	114.671
H4	C2	H5	109.801	H4	C2	H6	109.563
H5	C2	H6	109.405	H7	C3	H8	121.771

All results from a given calculation for CH₃OCH₂ (methoxymethyl radical)

using model chemistry: PBEPBE/6-31+G**

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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Number	Element	Mulliken
1	O	-0.198
2	C	-0.330
3	C	-0.260
4	H	0.174
5	H	0.170
6	H	0.160
7	H	0.152
8	H	0.133

	x	y	z	Total
	-1.037	1.008	-0.375	1.494
CHELPG
AIM
ESP

	x	y	z
x	5.840	0.164	0.008
y	0.164	4.223	0.029
z	0.008	0.029	4.556

<r²>	49.609
(<r²>)^1/2	7.043

All results from a given calculation for CH3OCH2 (methoxymethyl radical)

using model chemistry: PBEPBE/6-31+G**

States and conformations

All results from a given calculation for CH₃OCH₂ (methoxymethyl radical)