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S2C1
Vibrational Frequencies calculated at M06-2X/6-31+G**
Geometric Data calculated at M06-2X/6-31+G**
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability
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S1C1
Energy calculated at M06-2X/6-31+G**
| | hartrees |
| Energy at 0K | -77.156961 |
| Energy at 298.15K | -77.157047 |
| HF Energy | -77.156961 |
| Nuclear repulsion energy | 23.610176 |
The energy at 298.15K was derived from the energy at 0K
and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at M06-2X/6-31+G**
| Mode Number |
Symmetry |
Frequency (cm-1) |
Scaled Frequency (cm-1) |
IR Intensities (km mol-1) |
Raman Act (Å4/u) |
Dep P |
Dep U |
| 1 |
A1 |
3077 |
2930 |
2.30 |
|
|
|
| 2 |
A1 |
1639 |
1561 |
1.90 |
|
|
|
| 3 |
A1 |
1411 |
1343 |
2.95 |
|
|
|
| 4 |
B1 |
839 |
799 |
16.64 |
|
|
|
| 5 |
B2 |
3157 |
3006 |
2.87 |
|
|
|
| 6 |
B2 |
999 |
951 |
4.66 |
|
|
|
Unscaled Zero Point Vibrational Energy (zpe) 5560.9 cm
-1
Scaled (by 0.9522) Zero Point Vibrational Energy (zpe) 5295.1 cm
-1
See section
III.C.1 List or set vibrational scaling factors
to change the scale factors used here.
See section
III.C.2
Calculate a vibrational scaling factor for a given set of molecules
to determine the least squares best scaling factor.
Geometric Data calculated at M06-2X/6-31+G**
Point Group is C2v
Cartesians (Å)
| Atom |
x (Å) |
y (Å) |
z (Å) |
| C1 |
0.000 |
0.000 |
-0.483 |
| C2 |
0.000 |
0.000 |
0.832 |
| H3 |
0.000 |
0.935 |
-1.047 |
| H4 |
0.000 |
-0.935 |
-1.047 |
Atom - Atom Distances (Å)
| |
C1 |
C2 |
H3 |
H4 |
| C1 | | 1.3149 | 1.0923 | 1.0923 |
C2 | 1.3149 | | 2.0988 | 2.0988 | H3 | 1.0923 | 2.0988 | | 1.8710 | H4 | 1.0923 | 2.0988 | 1.8710 | |
More geometry information
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability
Charges from optimized geometry at M06-2X/6-31+G**
Charges (e)
| Number |
Element |
Mulliken |
CHELPG |
AIM |
ESP |
| 1 |
C |
-0.305 |
|
|
|
| 2 |
C |
-0.034 |
|
|
|
| 3 |
H |
0.170 |
|
|
|
| 4 |
H |
0.170 |
|
|
|
Electric dipole moments
Electric dipole components in Debye
(What's a Debye? See section
VII.A.3)
| |
x |
y |
z |
Total |
| |
0.000 |
0.000 |
-0.642 |
0.642 |
| CHELPG |
|
|
|
|
| AIM |
|
|
|
|
| ESP |
|
|
|
|
Electric Quadrupole moment
Quadrupole components in D Å
| Primitive |
| | x | y | z |
| x |
-14.223 |
0.000 |
0.000 |
| y |
0.000 |
-12.182 |
0.000 |
| z |
0.000 |
0.000 |
-11.433 |
|
| Traceless |
| | x | y | z |
| x |
-2.415 |
0.000 |
0.000 |
| y |
0.000 |
0.645 |
0.000 |
| z |
0.000 |
0.000 |
1.770 |
|
| Polar |
| 3z2-r2 | 3.540 |
| x2-y2 | -2.040 |
| xy | 0.000 |
| xz | 0.000 |
| yz | 0.000 |
|
Polarizabilities
Components of the polarizability tensor.
Units are
Å
3 (Angstrom cubed)
Change units.
| |
x |
y |
z |
| x |
2.633 |
0.000 |
0.000 |
| y |
0.000 |
2.500 |
0.000 |
| z |
0.000 |
0.000 |
4.391 |
<r2> (average value of r
2) Å
2
| <r2> |
17.372 |
| (<r2>)1/2 |
4.168 |