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	hartrees
Energy at 0K	-678.933059
Energy at 298.15K	-678.936820
HF Energy	-678.110246
Nuclear repulsion energy	268.572658

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A'	3240	3086	17.91
2	A'	1376	1310	76.59
3	A'	1160	1105	192.19
4	A'	879	837	176.26
5	A'	794	756	80.70
6	A'	498	474	55.23
7	A'	449	428	66.92
8	A'	342	326	65.86
9	A'	248	237	0.94
10	A"	3364	3204	12.81
11	A"	983	936	208.69
12	A"	808	769	0.12
13	A"	445	424	0.09
14	A"	351	334	21.42
15	A"	199	189	1.33

Atom	x (Å)	y (Å)	z (Å)
P1	-0.024	0.132	0.000
C2	-0.504	1.685	0.000
F3	1.491	-0.431	0.000
F4	-0.504	-0.703	1.268
F5	-0.504	-0.703	-1.268
H6	-0.485	2.223	-0.948
H7	-0.485	2.223	0.948

	P1	C2	F3	F4	F5	H6	H7
P1		1.6259	1.6166	1.5924	1.5924	2.3421	2.3421
C2	1.6259		2.9081	2.7046	2.7046	1.0903	1.0903
F3	1.6166	2.9081		2.3795	2.3795	3.4420	3.4420
F4	1.5924	2.7046	2.3795		2.5367	3.6712	2.9440
F5	1.5924	2.7046	2.3795	2.5367		2.9440	3.6712
H6	2.3421	1.0903	3.4420	3.6712	2.9440		1.8965
H7	2.3421	1.0903	3.4420	2.9440	3.6712	1.8965

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
P1	C2	H6	117.796	P1	C2	H7	117.796
C2	P1	F3	127.502	C2	P1	F4	114.358
C2	P1	F5	114.358	F3	P1	F4	95.719
F3	P1	F5	95.719	F4	P1	F5	105.596
H6	C2	H7	120.857

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)

using model chemistry: MP2/cc-pVDZ

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF3CH2 (phosphorane, trifluoromethylene-)

using model chemistry: MP2/cc-pVDZ

States and conformations

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)