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	hartrees
Energy at 0K	-2353.892222
Energy at 298.15K	-2353.899371
HF Energy	-2353.130104
Nuclear repulsion energy	292.847380

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A₁	3172	3011	22.51
2	A₁	3066	2911	16.91
3	A₁	1489	1414	8.60
4	A₁	1303	1238	5.31
5	A₁	909	863	25.37
6	A₁	604	574	2.24
7	A₁	235	223	1.20
8	A₂	3181	3020	0.00
9	A₂	1463	1389	0.00
10	A₂	762	724	0.00
11	A₂	145	138	0.00
12	E	3181	3020	7.67
12	E	3181	3020	7.67
13	E	3173	3013	2.48
13	E	3173	3013	2.48
14	E	3070	2915	12.98
14	E	3070	2915	12.98
15	E	1479	1404	7.93
15	E	1479	1404	7.93
16	E	1470	1396	4.14
16	E	1470	1396	4.14
17	E	1278	1214	1.08
17	E	1278	1214	1.08
18	E	911	865	13.74
18	E	911	865	13.74
19	E	803	763	0.28
19	E	803	763	0.28
20	E	622	590	16.68
20	E	622	590	16.68
21	E	220	209	0.25
21	E	220	209	0.25
22	E	173	164	0.03
22	E	173	164	0.03

Atom	x (Å)	y (Å)	z (Å)
As1	0.000	0.000	0.470
C2	0.000	1.681	-0.516
C3	1.456	-0.841	-0.516
C4	-1.456	-0.841	-0.516
H5	0.000	1.508	-1.591
H6	1.306	-0.754	-1.591
H7	-1.306	-0.754	-1.591
H8	-0.882	2.256	-0.242
H9	2.395	-0.364	-0.242
H10	-1.513	-1.892	-0.242
H11	0.882	2.256	-0.242
H12	1.513	-1.892	-0.242
H13	-2.395	-0.364	-0.242

	As1	C2	C3	C4	H5	H6	H7	H8	H9	H10	H11	H12	H13
As1		1.9487	1.9487	1.9487	2.5538	2.5538	2.5538	2.5250	2.5250	2.5250	2.5250	2.5250	2.5250
C2	1.9487		2.9120	2.9120	1.0892	2.9655	2.9655	1.0882	3.1616	3.8902	1.0882	3.8902	3.1616
C3	1.9487	2.9120		2.9120	2.9655	1.0892	2.9655	3.8902	1.0882	3.1616	3.1616	1.0882	3.8902
C4	1.9487	2.9120	2.9120		2.9655	2.9655	1.0892	3.1616	3.8902	1.0882	3.8902	3.1616	1.0882
H5	2.5538	1.0892	2.9655	2.9655		2.6127	2.6127	1.7772	3.3263	3.9591	1.7772	3.9591	3.3263
H6	2.5538	2.9655	1.0892	2.9655	2.6127		2.6127	3.9591	1.7772	3.3263	3.3263	1.7772	3.9591
H7	2.5538	2.9655	2.9655	1.0892	2.6127	2.6127		3.3263	3.9591	1.7772	3.9591	3.3263	1.7772
H8	2.5250	1.0882	3.8902	3.1616	1.7772	3.9591	3.3263		4.1963	4.1963	1.7644	4.7904	3.0260
H9	2.5250	3.1616	1.0882	3.8902	3.3263	1.7772	3.9591	4.1963		4.1963	3.0260	1.7644	4.7904
H10	2.5250	3.8902	3.1616	1.0882	3.9591	3.3263	1.7772	4.1963	4.1963		4.7904	3.0260	1.7644
H11	2.5250	1.0882	3.1616	3.8902	1.7772	3.3263	3.9591	1.7644	3.0260	4.7904		4.1963	4.1963
H12	2.5250	3.8902	1.0882	3.1616	3.9591	1.7772	3.3263	4.7904	1.7644	3.0260	4.1963		4.1963
H13	2.5250	3.1616	3.8902	1.0882	3.3263	3.9591	1.7772	3.0260	4.7904	1.7644	4.1963	4.1963

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
As1	C2	H5	111.245	As1	C2	H8	109.190
As1	C2	H11	109.190	As1	C3	H6	111.245
As1	C3	H9	109.190	As1	C3	H12	109.190
As1	C4	H7	111.245	As1	C4	H10	109.190
As1	C4	H13	109.190	C2	As1	C3	96.690
C2	As1	C4	96.690	C3	As1	C4	96.690
H5	C2	H8	109.416	H5	C2	H11	109.416
H6	C3	H9	109.416	H6	C3	H12	109.416
H7	C4	H10	109.416	H7	C4	H13	109.416
H8	C2	H11	108.331	H9	C3	H12	108.331
H10	C4	H13	108.331

All results from a given calculation for As(CH₃)₃ (trimethyl arsine)

using model chemistry: MP2/cc-pVTZ

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for As(CH3)3 (trimethyl arsine)

using model chemistry: MP2/cc-pVTZ

States and conformations

All results from a given calculation for As(CH₃)₃ (trimethyl arsine)