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	hartrees
Energy at 0K	-275.748341
Energy at 298.15K	-275.752197
HF Energy	-275.748341
Nuclear repulsion energy	73.731962

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A₁	2891	2745	344.34
2	A₁	1555	1477	154.18
3	A₁	1172	1113	274.85
4	A₁	539	512	14.28
5	E	2894	2748	153.35
5	E	2894	2748	153.33
6	E	1580	1500	2.89
6	E	1580	1500	2.89
7	E	1191	1131	9.62
7	E	1191	1131	9.62
8	E	138	131	30.06
8	E	138	131	30.06

Atom	x (Å)	y (Å)	z (Å)
Na1	0.000	0.000	1.634
O2	0.000	0.000	-0.238
C3	0.000	0.000	-1.638
H4	0.000	1.017	-2.082
H5	0.881	-0.509	-2.082
H6	-0.881	-0.509	-2.082

	Na1	O2	C3	H4	H5	H6
Na1		1.8717	3.2722	3.8531	3.8531	3.8531
O2	1.8717		1.4005	2.1065	2.1065	2.1065
C3	3.2722	1.4005		1.1101	1.1101	1.1101
H4	3.8531	2.1065	1.1101		1.7622	1.7622
H5	3.8531	2.1065	1.1101	1.7622		1.7622
H6	3.8531	2.1065	1.1101	1.7622	1.7622

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
Na1	O2	C3	180.000	O2	C3	H4	113.581
O2	C3	H5	113.581	O2	C3	H6	113.581
H4	C3	H5	105.067	H4	C3	H6	105.067
H5	C3	H6	105.067

All results from a given calculation for NaOCH₃ (Sodium methoxide)

using model chemistry: mPW1PW91/3-21G*

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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Number	Element	Mulliken
1	Na	0.483
2	O	-0.602
3	C	-0.311
4	H	0.143
5	H	0.143
6	H	0.143

	x	y	z	Total
	0.000	0.000	6.166	6.166
CHELPG
AIM
ESP

	x	y	z
x	3.926	0.000	0.000
y	0.000	3.926	0.001
z	0.000	0.001	6.596

<r²>	71.412
(<r²>)^1/2	8.451

All results from a given calculation for NaOCH3 (Sodium methoxide)

using model chemistry: mPW1PW91/3-21G*

States and conformations

All results from a given calculation for NaOCH₃ (Sodium methoxide)