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	hartrees
Energy at 0K	-189.380098
Energy at 298.15K	-189.390281
Nuclear repulsion energy	135.582308

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A	3485	3309	0.95
2	A	3145	2987	2.02
3	A	3100	2944	5.39
4	A	3010	2858	109.32
5	A	1590	1510	2.70
6	A	1560	1481	1.49
7	A	1555	1477	0.53
8	A	1491	1416	0.47
9	A	1264	1200	16.02
10	A	1149	1091	5.85
11	A	1120	1063	1.15
12	A	948	900	29.98
13	A	633	601	174.92
14	A	332	315	14.85
15	A	286	272	1.52
16	A	168	160	0.19
17	B	3503	3327	0.07
18	B	3145	2987	43.77
19	B	3101	2944	63.79
20	B	2994	2843	9.73
21	B	1587	1507	14.45
22	B	1551	1473	22.28
23	B	1478	1403	0.25
24	B	1472	1398	1.26
25	B	1175	1115	10.95
26	B	1141	1084	20.41
27	B	1007	956	0.18
28	B	685	650	43.17
29	B	474	450	7.58
30	B	217	206	2.20

Atom	x (Å)	y (Å)	z (Å)
N1	-0.164	0.705	-0.689
N2	0.164	-0.705	-0.689
C3	0.164	1.448	0.540
C4	-0.164	-1.448	0.540
H5	-1.147	0.796	-0.948
H6	1.147	-0.796	-0.948
H7	-0.112	2.495	0.381
H8	-0.329	1.096	1.459
H9	1.247	1.406	0.694
H10	0.112	-2.495	0.381
H11	0.329	-1.096	1.459
H12	-1.247	-1.406	0.694

	N1	N2	C3	C4	H5	H6	H7	H8	H9	H10	H11	H12
N1		1.4471	1.4740	2.4792	1.0200	2.0097	2.0865	2.1903	2.0969	3.3851	2.8464	2.7457
N2	1.4471		2.4792	1.4740	2.0097	1.0200	3.3851	2.8464	2.7457	2.0865	2.1903	2.0969
C3	1.4740	2.4792		2.9152	2.0882	2.8667	1.0940	1.1017	1.0943	3.9468	2.7099	3.1878
C4	2.4792	1.4740	2.9152		2.8667	2.0882	3.9468	2.7099	3.1878	1.0940	1.1017	1.0943
H5	1.0200	2.0097	2.0882	2.8667		2.7921	2.3928	2.5604	2.9663	3.7659	3.3993	2.7486
H6	2.0097	1.0200	2.8667	2.0882	2.7921		3.7659	3.3993	2.7486	2.3928	2.5604	2.9663
H7	2.0865	3.3851	1.0940	3.9468	2.3928	3.7659		1.7801	1.7692	4.9948	3.7748	4.0747
H8	2.1903	2.8464	1.1017	2.7099	2.5604	3.3993	1.7801		1.7800	3.7748	2.2880	2.7723
H9	2.0969	2.7457	1.0943	3.1878	2.9663	2.7486	1.7692	1.7800		4.0747	2.7723	3.7585
H10	3.3851	2.0865	3.9468	1.0940	3.7659	2.3928	4.9948	3.7748	4.0747		1.7801	1.7692
H11	2.8464	2.1903	2.7099	1.1017	3.3993	2.5604	3.7748	2.2880	2.7723	1.7801		1.7800
H12	2.7457	2.0969	3.1878	1.0943	2.7486	2.9663	4.0747	2.7723	3.7585	1.7692	1.7800

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
N1	N2	C4	116.142	N1	N2	H6	107.831
N1	C3	H7	107.767	N1	C3	H8	115.750
N1	C3	H9	108.558	N2	N1	C3	116.142
N2	N1	H5	107.831	N2	C4	H10	107.767
N2	C4	H11	115.750	N2	C4	H12	108.558
C3	N1	H5	112.431	C4	N2	H6	112.431
H7	C3	H8	108.329	H7	C3	H9	107.891
H8	C3	H9	108.299	H10	C4	H11	108.329
H10	C4	H12	107.891	H11	C4	H12	108.299

All results from a given calculation for CH₃NHNHCH₃ (dimethyl hydrazine)

using model chemistry: mPW1PW91/3-21G*

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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Number	Element	Mulliken
1	N	-0.466
2	N	-0.466
3	C	-0.471
4	C	-0.471
5	H	0.307
6	H	0.307
7	H	0.224
8	H	0.186
9	H	0.220
10	H	0.224
11	H	0.186
12	H	0.220

	x	y	z	Total
	0.000	0.000	1.741	1.741
CHELPG
AIM
ESP

	x	y	z
x	4.615	-0.288	0.000
y	-0.288	5.917	0.000
z	0.000	0.000	4.501

<r²>	92.542
(<r²>)^1/2	9.620

All results from a given calculation for CH3NHNHCH3 (dimethyl hydrazine)

using model chemistry: mPW1PW91/3-21G*

States and conformations

All results from a given calculation for CH₃NHNHCH₃ (dimethyl hydrazine)