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All results from a given calculation for F2O (Difluorine monoxide)

using model chemistry: HF/6-311+G(3df,2p)

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes C2V 1A1
Energy calculated at HF/6-311+G(3df,2p)
 hartrees
Energy at 0K-273.556981
Energy at 298.15K-273.557978
Nuclear repulsion energy77.791769
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at HF/6-311+G(3df,2p)
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A1 1223 1112 13.99      
2 A1 601 546 1.75      
3 B2 1216 1105 86.12      

Unscaled Zero Point Vibrational Energy (zpe) 1520.2 cm-1
Scaled (by 0.9086) Zero Point Vibrational Energy (zpe) 1381.3 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at HF/6-311+G(3df,2p)
ABC
2.20673 0.40652 0.34328

See section I.F.4 to change rotational constant units
Geometric Data calculated at HF/6-311+G(3df,2p)

Point Group is C2v

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
O1 0.000 0.000 0.570
F2 0.000 1.045 -0.253
F3 0.000 -1.045 -0.253

Atom - Atom Distances (Å)
  O1 F2 F3
O11.33041.3304
F21.33042.0894
F31.33042.0894

picture of Difluorine monoxide state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
F2 O1 F3 103.483
Electronic energy levels

Electronic state

Charges, Dipole, Quadrupole and Polarizability
Charges from optimized geometry at HF/6-311+G(3df,2p) Charges (e)
Number Element Mulliken CHELPG AIM ESP
1 O 0.298      
2 F -0.149      
3 F -0.149      


Electric dipole moments
Electric dipole components in Debye
(What's a Debye? See section VII.A.3)
  x y z Total
  0.000 0.000 0.292 0.292
CHELPG        
AIM        
ESP        


Electric Quadrupole moment
Quadrupole components in D Å


Polarizabilities
Components of the polarizability tensor.
Units are Å3 (Angstrom cubed)
Change units.
  x y z
x 1.143 0.000 0.000
y 0.000 2.543 0.000
z 0.000 0.000 1.646


<r2> (average value of r2) Å2
<r2> 32.520
(<r2>)1/2 5.703