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	hartrees
Energy at 0K	-679.173110
Energy at 298.15K	-679.176954
HF Energy	-678.249728
Nuclear repulsion energy	271.857402

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)
1	A'	3202	3084
2	A'	1392	1341
3	A'	1134	1092
4	A'	868	836
5	A'	788	759
6	A'	534	514
7	A'	469	452
8	A'	345	333
9	A'	244	235
10	A"	3316	3194
11	A"	977	941
12	A"	823	793
13	A"	455	438
14	A"	357	344
15	A"	217	209

Atom	x (Å)	y (Å)	z (Å)
P1	-0.017	0.128	0.000
C2	-0.501	1.681	0.000
F3	1.467	-0.446	0.000
F4	-0.501	-0.690	1.248
F5	-0.501	-0.690	-1.248
H6	-0.457	2.217	-0.937
H7	-0.457	2.217	0.937

	P1	C2	F3	F4	F5	H6	H7
P1		1.6274	1.5908	1.5684	1.5684	2.3317	2.3317
C2	1.6274		2.8984	2.6791	2.6791	1.0801	1.0801
F3	1.5908	2.8984		2.3432	2.3432	3.4165	3.4165
F4	1.5684	2.6791	2.3432		2.4956	3.6364	2.9236
F5	1.5684	2.6791	2.3432	2.4956		2.9236	3.6364
H6	2.3317	1.0801	3.4165	3.6364	2.9236		1.8735
H7	2.3317	1.0801	3.4165	2.9236	3.6364	1.8735

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
P1	C2	H6	117.475	P1	C2	H7	117.475
C2	P1	F3	128.477	C2	P1	F4	113.916
C2	P1	F5	113.916	F3	P1	F4	95.751
F3	P1	F5	95.751	F4	P1	F5	105.421
H6	C2	H7	120.287

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)

using model chemistry: QCISD(T)/TZVP

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF3CH2 (phosphorane, trifluoromethylene-)

using model chemistry: QCISD(T)/TZVP

States and conformations

All results from a given calculation for PF₃CH₂ (phosphorane, trifluoromethylene-)