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	hartrees
Energy at 0K	-840.000437
Energy at 298.15K
HF Energy	-838.298285
Nuclear repulsion energy	408.210895

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁'	813	767	0.00	12.07	0.00	0.00
2	A₁'	650	613	0.00	1.57	0.73	0.85
3	A₂"	959	904	413.89	0.00	0.00	0.00
4	A₂"	570	537	58.04	0.00	0.00	0.00
5	E'	1030	971	273.10	0.68	0.75	0.86
5	E'	1030	971	273.10	0.68	0.75	0.86
6	E'	531	501	39.73	0.41	0.75	0.86
6	E'	531	501	39.73	0.41	0.75	0.86
7	E'	169	160	0.09	0.22	0.75	0.86
7	E'	169	160	0.09	0.22	0.75	0.86
8	E"	507	478	0.00	0.69	0.75	0.86
8	E"	507	478	0.00	0.69	0.75	0.86

Atom	x (Å)	y (Å)	z (Å)
P1	0.000	0.000	0.000
F2	0.000	1.539	0.000
F3	1.333	-0.769	0.000
F4	-1.333	-0.769	0.000
F5	0.000	0.000	1.579
F6	0.000	0.000	-1.579

	P1	F2	F3	F4	F5	F6
P1		1.5387	1.5387	1.5387	1.5793	1.5793
F2	1.5387		2.6651	2.6651	2.2050	2.2050
F3	1.5387	2.6651		2.6651	2.2050	2.2050
F4	1.5387	2.6651	2.6651		2.2050	2.2050
F5	1.5793	2.2050	2.2050	2.2050		3.1587
F6	1.5793	2.2050	2.2050	2.2050	3.1587

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
F2	P1	F3	120.000	F2	P1	F4	120.000
F2	P1	F5	90.000	F2	P1	F6	90.000
F3	P1	F4	120.000	F3	P1	F5	90.000
F3	P1	F6	90.000	F4	P1	F5	90.000
F4	P1	F6	90.000	F5	P1	F6	180.000

All results from a given calculation for PF₅ (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/6-311+G(3df,2p)

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for PF5 (Phosphorus pentafluoride)

using model chemistry: MP2=FULL/6-311+G(3df,2p)

States and conformations

All results from a given calculation for PF₅ (Phosphorus pentafluoride)