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	hartrees
Energy at 0K	-277.408545
Energy at 298.15K	-277.412231
HF Energy	-277.408545
Nuclear repulsion energy	73.328269

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A₁	2853	2729	371.93
2	A₁	1500	1435	105.74
3	A₁	1230	1177	316.62
4	A₁	480	459	33.55
5	E	2855	2731	208.05
5	E	2855	2731	208.05
6	E	1484	1420	2.90
6	E	1484	1420	2.90
7	E	1186	1134	1.48
7	E	1186	1134	1.48
8	E	99	95	31.69
8	E	99	95	31.69

Atom	x (Å)	y (Å)	z (Å)
Na1	0.000	0.000	1.663
O2	0.000	0.000	-0.277
C3	0.000	0.000	-1.638
H4	0.000	1.018	-2.084
H5	0.882	-0.509	-2.084
H6	-0.882	-0.509	-2.084

	Na1	O2	C3	H4	H5	H6
Na1		1.9400	3.3014	3.8834	3.8834	3.8834
O2	1.9400		1.3614	2.0746	2.0746	2.0746
C3	3.3014	1.3614		1.1116	1.1116	1.1116
H4	3.8834	2.0746	1.1116		1.7635	1.7635
H5	3.8834	2.0746	1.1116	1.7635		1.7635
H6	3.8834	2.0746	1.1116	1.7635	1.7635

atom1	atom2	atom3	angle	atom1	atom2	atom3	angle
Na1	O2	C3	180.000	O2	C3	H4	113.665
O2	C3	H5	113.665	O2	C3	H6	113.665
H4	C3	H5	104.971	H4	C3	H6	104.971
H5	C3	H6	104.971

All results from a given calculation for NaOCH₃ (Sodium methoxide)

using model chemistry: mPW1PW91/6-311G**

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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Number	Element	Mulliken
1	Na	0.683
2	O	-0.715
3	C	-0.072
4	H	0.035
5	H	0.035
6	H	0.035

	x	y	z	Total
	0.000	0.000	7.321	7.321
CHELPG
AIM
ESP

	x	y	z
x	3.878	0.000	0.000
y	0.000	3.878	0.001
z	0.000	0.001	6.236

<r²>	72.657
(<r²>)^1/2	8.524

All results from a given calculation for NaOCH3 (Sodium methoxide)

using model chemistry: mPW1PW91/6-311G**

States and conformations

All results from a given calculation for NaOCH₃ (Sodium methoxide)