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	hartrees
Energy at 0K	-474.798084
Energy at 298.15K
HF Energy	-474.395852
Nuclear repulsion energy	78.600825

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)	Raman Act (Å⁴/u)	Dep P	Dep U
1	A₁	3190	3031	26.11	172.13	0.15	0.25
2	A₁	1827	1736	334.07	2.25	0.00	0.00
3	A₁	1395	1325	1.47	11.61	0.60	0.75
4	A₁	871	827	4.39	29.48	0.28	0.44
5	B₁	674	641	93.59	1.09	0.75	0.86
6	B₁	401	381	3.58	0.25	0.75	0.86
7	B₂	3288	3124	3.14	101.60	0.75	0.86
8	B₂	940	893	0.09	0.56	0.75	0.86
9	B₂	357	339	3.38	0.39	0.75	0.86

Atom	y (Å)	z (Å)
C1	0.000	-1.763
C2	0.000	-0.443
S3	0.000	1.116
H4	0.937	-2.308
H5	-0.937	-2.308

	C1	C2	S3	H4	H5
C1		1.3199	2.8795	1.0842	1.0842
C2	1.3199		1.5595	2.0873	2.0873
S3	2.8795	1.5595		3.5505	3.5505
H4	1.0842	2.0873	3.5505		1.8744
H5	1.0842	2.0873	3.5505	1.8744

atom1	atom2	atom3	angle		atom1	atom2	atom3	angle
C1	C2	S3	180.000		C2	C1	H4	120.185
C2	C1	H5	120.185		H4	C1	H5	119.630

All results from a given calculation for CH₂CS (Thioketene)

using model chemistry: MP2/6-311G**

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for CH2CS (Thioketene)

using model chemistry: MP2/6-311G**

States and conformations

All results from a given calculation for CH₂CS (Thioketene)