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All results from a given calculation for GaF3 (Gallium trifluoride)

using model chemistry: CCD/6-311G*

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes D3H 1A1'
Energy calculated at CCD/6-311G*
 hartrees
Energy at 0K-2222.388319
Energy at 298.15K-2222.389549
HF Energy-2221.721933
Nuclear repulsion energy297.290728
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at CCD/6-311G*
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A1' 678 647 0.00      
2 A2" 212 203 80.33      
3 E' 772 737 101.14      
3 E' 772 737 101.14      
4 E' 194 186 40.07      
4 E' 194 186 40.07      

Unscaled Zero Point Vibrational Energy (zpe) 1411.2 cm-1
Scaled (by 0.9551) Zero Point Vibrational Energy (zpe) 1347.8 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at CCD/6-311G*
ABC
0.19548 0.19548 0.09774

See section I.F.4 to change rotational constant units
Geometric Data calculated at CCD/6-311G*

Point Group is D3h

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
Ga1 0.000 0.000 0.000
F2 0.000 1.740 0.000
F3 1.507 -0.870 0.000
F4 -1.507 -0.870 0.000

Atom - Atom Distances (Å)
  Ga1 F2 F3 F4
Ga11.73961.73961.7396
F21.73963.01313.0131
F31.73963.01313.0131
F41.73963.01313.0131

picture of Gallium trifluoride state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
F2 Ga1 F3 120.000 F2 Ga1 F4 120.000
F3 Ga1 F4 120.000
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability