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	hartrees
Energy at 0K	-474.821439
Energy at 298.15K
HF Energy	-474.400887
Nuclear repulsion energy	78.844148

Mode Number	Symmetry	Frequency (cm^-1)	Scaled Frequency (cm^-1)	IR Intensities (km mol^-1)
1	A₁	3223	3014	17.66
2	A₁	1851	1731	358.07
3	A₁	1434	1341	0.00
4	A₁	877	820	12.77
5	B₁	714	668	90.52
6	B₁	381	357	4.69
7	B₂	3314	3099	1.56
8	B₂	964	901	0.71
9	B₂	355	332	3.27

Atom	y (Å)	z (Å)
C1	0.000	-1.755
C2	0.000	-0.447
S3	0.000	1.113
H4	0.931	-2.301
H5	-0.931	-2.301

	C1	C2	S3	H4	H5
C1		1.3083	2.8685	1.0793	1.0793
C2	1.3083		1.5602	2.0748	2.0748
S3	2.8685	1.5602		3.5390	3.5390
H4	1.0793	2.0748	3.5390		1.8623
H5	1.0793	2.0748	3.5390	1.8623

atom1	atom2	atom3	angle		atom1	atom2	atom3	angle
C1	C2	S3	180.000		C2	C1	H4	120.374
C2	C1	H5	120.374		H4	C1	H5	119.251

All results from a given calculation for CH₂CS (Thioketene)

using model chemistry: MP3/TZVP

States and conformations

	Computational Chemistry Comparison and Benchmark DataBase Release 22 (May 2022) Standard Reference Database 101 National Institute of Standards and Technology
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All results from a given calculation for CH2CS (Thioketene)

using model chemistry: MP3/TZVP

States and conformations

All results from a given calculation for CH₂CS (Thioketene)