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All results from a given calculation for ClSO (Sulfur chloride oxide)

using model chemistry: QCISD(T)=FULL/aug-cc-pVQZ

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes CS 2A"
Energy calculated at QCISD(T)=FULL/aug-cc-pVQZ
 hartrees
Energy at 0K-932.791455
Energy at 298.15K-932.792016
HF Energy-931.938303
Nuclear repulsion energy140.789717
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at QCISD(T)=FULL/aug-cc-pVQZ
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A' 1179 1179        
2 A' 495 495        
3 A' 303 303        

Unscaled Zero Point Vibrational Energy (zpe) 988.6 cm-1
Scaled (by 1) Zero Point Vibrational Energy (zpe) 988.6 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at QCISD(T)=FULL/aug-cc-pVQZ
ABC
1.07543 0.15097 0.13239

See section I.F.4 to change rotational constant units
Geometric Data calculated at QCISD(T)=FULL/aug-cc-pVQZ

Point Group is Cs

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
Cl1 -0.691 -1.136 0.000
S2 0.000 0.804 0.000
O3 1.469 0.805 0.000

Atom - Atom Distances (Å)
  Cl1 S2 O3
Cl12.05942.9037
S22.05941.4689
O32.90371.4689

picture of Sulfur chloride oxide state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
Cl1 S2 O3 109.632
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability