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All results from a given calculation for NF2 (Difluoroamino radical)

using model chemistry: B3LYP/6-31G**

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes C2V 2B1
Energy calculated at B3LYP/6-31G**
 hartrees
Energy at 0K-254.262472
Energy at 298.15K-254.263398
HF Energy-254.262472
Nuclear repulsion energy69.131351
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at B3LYP/6-31G**
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A1 1118 1075 57.59      
2 A1 565 543 0.98      
3 B2 980 942 229.61      

Unscaled Zero Point Vibrational Energy (zpe) 1331.7 cm-1
Scaled (by 0.9608) Zero Point Vibrational Energy (zpe) 1279.5 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at B3LYP/6-31G**
ABC
2.31945 0.38982 0.33373

See section I.F.4 to change rotational constant units
Geometric Data calculated at B3LYP/6-31G**

Point Group is C2v

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
N1 0.000 0.000 0.607
F2 0.000 1.067 -0.236
F3 0.000 -1.067 -0.236

Atom - Atom Distances (Å)
  N1 F2 F3
N11.35961.3596
F21.35962.1337
F31.35962.1337

picture of Difluoroamino radical state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
F2 N1 F3 103.383
Electronic energy levels

Electronic state

Charges, Dipole, Quadrupole and Polarizability
Charges from optimized geometry at B3LYP/6-31G** Charges (e)
Number Element Mulliken CHELPG AIM ESP
1 N 0.356      
2 F -0.178      
3 F -0.178      


Electric dipole moments
Electric dipole components in Debye
(What's a Debye? See section VII.A.3)
  x y z Total
  0.000 0.000 -0.017 0.017
CHELPG        
AIM        
ESP        


Electric Quadrupole moment
Quadrupole components in D Å
Primitive
 xyz
x -14.309 0.000 0.000
y 0.000 -14.897 0.000
z 0.000 0.000 -14.977
Traceless
 xyz
x 0.628 0.000 0.000
y 0.000 -0.254 0.000
z 0.000 0.000 -0.374
Polar
3z2-r2-0.748
x2-y20.588
xy0.000
xz0.000
yz0.000


Polarizabilities
Components of the polarizability tensor.
Units are Å3 (Angstrom cubed)
Change units.
  x y z
x 0.984 0.000 0.000
y 0.000 2.234 0.000
z 0.000 0.000 1.425


<r2> (average value of r2) Å2
<r2> 33.265
(<r2>)1/2 5.768