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All results from a given calculation for HSiF (fluorosilylene)

using model chemistry: B97D3/aug-cc-pVDZ

19 10 17 12 22

States and conformations

State Conformation minimum conformation conformer description state description
1 1 yes CS 1A'
Energy calculated at B97D3/aug-cc-pVDZ
 hartrees
Energy at 0K-389.887860
Energy at 298.15K 
HF Energy-389.887860
Nuclear repulsion energy46.357225
The energy at 298.15K was derived from the energy at 0K and an integrated heat capacity that used the calculated vibrational frequencies.
Vibrational Frequencies calculated at B97D3/aug-cc-pVDZ
Mode Number Symmetry Frequency
(cm-1)
Scaled Frequency
(cm-1)
IR Intensities
(km mol-1)
Raman Act
4/u)
Dep P Dep U
1 A' 1886 1886 398.04 254.71 0.37 0.54
2 A' 819 819 56.44 15.76 0.52 0.69
3 A' 762 762 113.60 9.76 0.64 0.78

Unscaled Zero Point Vibrational Energy (zpe) 1733.6 cm-1
Scaled (by 1) Zero Point Vibrational Energy (zpe) 1733.6 cm-1
See section III.C.1 List or set vibrational scaling factors to change the scale factors used here.
See section III.C.2 Calculate a vibrational scaling factor for a given set of molecules to determine the least squares best scaling factor.
Rotational Constants (cm-1) from geometry optimized at B97D3/aug-cc-pVDZ
ABC
7.23336 0.51456 0.48039

See section I.F.4 to change rotational constant units
Geometric Data calculated at B97D3/aug-cc-pVDZ

Point Group is Cs

Cartesians (Å)
Atom x (Å) y (Å) z (Å)
Si1 0.065 -0.624 0.000
F2 0.065 1.058 0.000
H3 -1.490 -0.781 0.000

Atom - Atom Distances (Å)
  Si1 F2 H3
Si11.68211.5626
F21.68212.4081
H31.56262.4081

picture of fluorosilylene state 1 conformation 1
More geometry information
Calculated Bond Angles
atom1 atom2 atom3 angle atom1 atom2 atom3 angle
F2 Si1 H3 95.762
Electronic energy levels
Charges, Dipole, Quadrupole and Polarizability
Charges from optimized geometry at B97D3/aug-cc-pVDZ Charges (e)
Number Element Mulliken CHELPG AIM ESP
1 Si 0.344      
2 F -0.455      
3 H 0.111      


Electric dipole moments
Electric dipole components in Debye
(What's a Debye? See section VII.A.3)
  x y z Total
  -0.152 -1.242 0.000 1.251
CHELPG        
AIM        
ESP        


Electric Quadrupole moment
Quadrupole components in D Å
Primitive
 xyz
x -20.900 0.641 0.000
y 0.641 -20.400 0.000
z 0.000 0.000 -16.302
Traceless
 xyz
x -2.549 0.641 0.000
y 0.641 -1.800 0.000
z 0.000 0.000 4.348
Polar
3z2-r28.697
x2-y2-0.499
xy0.641
xz0.000
yz0.000


Polarizabilities
Components of the polarizability tensor.
Units are Å3 (Angstrom cubed)
Change units.
  x y z
x 5.694 0.102 0.000
y 0.102 4.839 0.000
z 0.000 0.000 4.402


<r2> (average value of r2) Å2
<r2> 30.446
(<r2>)1/2 5.518