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Geometry for SF5Cl (sulfur chloropentafluoride) 1A1 C4V

1910171554
InChI=1S/ClF5S/c1-7(2,3,4,5)6 INChIKey=GSYNTTDHMKSMFY-UHFFFAOYSA-N

CBS-Q


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 -0.2485   -0.2485 0.0000 0.0000
Cl2 0.0000 0.0000 1.7811   1.7811 0.0000 0.0000
F3 0.0000 1.5695 -0.2774   -0.2774 1.5695 0.0000
F4 1.5695 0.0000 -0.2774   -0.2774 0.0000 1.5695
F5 0.0000 -1.5695 -0.2774   -0.2774 -1.5695 0.0000
F6 -1.5695 0.0000 -0.2774   -0.2774 0.0000 -1.5695
F7 0.0000 0.0000 -1.8130   -1.8130 0.0000 0.0000
Atom - Atom Distances (Å)
  S1 Cl2 F3 F4 F5 F6 F7
S1 2.0296 1.5697 1.5697 1.5697 1.5697 1.5645
Cl2 2.0296 2.5885 2.5885 2.5885 2.5885 3.5941
F3 1.5697 2.5885 2.2195 3.1389 2.2195 2.1958
F4 1.5697 2.5885 2.2195 2.2195 3.1389 2.1958
F5 1.5697 2.5885 3.1389 2.2195 2.2195 2.1958
F6 1.5697 2.5885 2.2195 3.1389 2.2195 2.1958
F7 1.5645 3.5941 2.1958 2.1958 2.1958 2.1958
Maximum atom distance is 3.5941Å between atoms Cl2 and F7.
picture of sulfur chloropentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl2 S1 F3 91.054 Cl2 S1 F4 91.054
Cl2 S1 F5 91.054 Cl2 S1 F6 91.054
Cl2 S1 F7 180.000 F3 S1 F4 89.981
F3 S1 F5 177.892 F3 S1 F6 89.981
F3 S1 F7 88.946 F4 S1 F5 89.981
F4 S1 F6 177.892 F4 S1 F7 88.946
F5 S1 F6 89.981 F5 S1 F7 88.946
F6 S1 F7 88.946

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.