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Geometry for SOF4 (Sulfur tetrafluoride oxide) 1A1 C2V

1910171554
InChI=1S/F4OS/c1-6(2,3,4)5 INChIKey=DUGWRBKBGKTKOX-UHFFFAOYSA-N

B3PW91/6-31G*


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.1412   0.0000 0.0000 0.1412
O2 0.0000 0.0000 1.5762   0.0000 0.0000 1.5762
F3 0.0000 1.6033 -0.1009   1.6033 0.0000 -0.1009
F4 0.0000 -1.6033 -0.1009   -1.6033 0.0000 -0.1009
F5 1.3318 0.0000 -0.7251   0.0000 1.3318 -0.7251
F6 -1.3318 0.0000 -0.7251   0.0000 -1.3318 -0.7251
Atom - Atom Distances (Å)
  S1 O2 F3 F4 F5 F6
S1 1.4350 1.6215 1.6215 1.5887 1.5887
O2 1.4350 2.3202 2.3202 2.6588 2.6588
F3 1.6215 2.3202 3.2066 2.1757 2.1757
F4 1.6215 2.3202 3.2066 2.1757 2.1757
F5 1.5887 2.6588 2.1757 2.1757 2.6636
F6 1.5887 2.6588 2.1757 2.1757 2.6636
Maximum atom distance is 3.2066Å between atoms F3 and F4.
picture of Sulfur tetrafluoride oxide
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
O2 S1 F3 98.587 O2 S1 F4 98.587
O2 S1 F5 123.040 O2 S1 F6 123.040
F3 S1 F4 162.826 F3 S1 F5 85.330
F3 S1 F6 85.330 F4 S1 F5 85.330
F4 S1 F6 85.330 F5 S1 F6 113.919

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.