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Geometry for CH3NHNHCH3 (dimethyl hydrazine) 1A C2

1910171554
InChI=1S/C2H8N2/c1-3-4-2/h3-4H,1-2H3 INChIKey=DIIIISSCIXVANO-UHFFFAOYSA-N

MP2/6-31G*


Point group is C2
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
N1 -0.1600 0.6864 -0.6871   -0.6808 -0.1849 0.6864
N2 0.1600 -0.6864 -0.6871   -0.6925 0.1348 -0.6864
C3 0.1600 1.4305 0.5320   0.5258 0.1792 1.4305
C4 -0.1600 -1.4305 0.5320   0.5375 -0.1405 -1.4305
H5 -1.1515 0.7840 -0.8995   -0.8570 -1.1835 0.7840
H6 1.1515 -0.7840 -0.8995   -0.9408 1.1180 -0.7840
H7 -0.0996 2.4765 0.3581   0.3614 -0.0865 2.4765
H8 -0.3540 1.0947 1.4456   1.4575 -0.3011 1.0947
H9 1.2370 1.3752 0.7135   0.6680 1.2622 1.3752
H10 0.0996 -2.4765 0.3581   0.3542 0.1125 -2.4765
H11 0.3540 -1.0947 1.4456   1.4317 0.4064 -1.0947
H12 -1.2370 -1.3752 0.7135   0.7581 -1.2102 -1.3752
Atom - Atom Distances (Å)
  N1 N2 C3 C4 H5 H6 H7 H8 H9 H10 H11 H12
N1 1.4096 1.4637 2.4428 1.0187 1.9817 2.0738 2.1801 2.0947 3.3412 2.8257 2.7151
N2 1.4096 2.4428 1.4637 1.9817 1.0187 3.3412 2.8257 2.7151 2.0738 2.1801 2.0947
C3 1.4637 2.4428 2.8788 2.0462 2.8172 1.0917 1.1007 1.0936 3.9113 2.6923 3.1394
C4 2.4428 1.4637 2.8788 2.8172 2.0462 3.9113 2.6923 3.1394 1.0917 1.1007 1.0936
H5 1.0187 1.9817 2.0462 2.8172 2.7861 2.3564 2.4964 2.9421 3.7118 3.3608 2.6965
H6 1.9817 1.0187 2.8172 2.0462 2.7861 3.7118 3.3608 2.6965 2.3564 2.4964 2.9421
H7 2.0738 3.3412 1.0917 3.9113 2.3564 3.7118 1.7768 1.7679 4.9570 3.7605 4.0318
H8 2.1801 2.8257 1.1007 2.6923 2.4964 3.3608 1.7768 1.7736 3.7605 2.3010 2.7232
H9 2.0947 2.7151 1.0936 3.1394 2.9421 2.6965 1.7679 1.7736 4.0318 2.7232 3.6993
H10 3.3412 2.0738 3.9113 1.0917 3.7118 2.3564 4.9570 3.7605 4.0318 1.7768 1.7679
H11 2.8257 2.1801 2.6923 1.1007 3.3608 2.4964 3.7605 2.3010 2.7232 1.7768 1.7736
H12 2.7151 2.0947 3.1394 1.0936 2.6965 2.9421 4.0318 2.7232 3.6993 1.7679 1.7736
Maximum atom distance is 4.9570Å between atoms H7 and H10.
picture of dimethyl hydrazine
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
N1 N2 C4 116.456 N2 N1 C3 116.456
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
N1 N2 H6 108.313 N1 C3 H7 107.603
N1 C3 H8 115.732 N1 C3 H9 109.134
N2 N1 H5 108.313 N2 C4 H10 107.603
N2 C4 H11 115.732 N2 C4 H12 109.134
C3 N1 H5 109.736 C4 N2 H6 109.736
H7 C3 H8 108.277 H7 C3 H9 108.002
H8 C3 H9 107.858 H10 C4 H11 108.277
H10 C4 H12 108.002 H11 C4 H12 107.858

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.