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Geometry for SF4 (Sulfur tetrafluoride) 1A1 C2V

1910171554
InChI=1S/F4S/c1-5(2,3)4 INChIKey=QHMQWEPBXSHHLH-UHFFFAOYSA-N

PBEPBEultrafine/6-31G*


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.3921   0.0000 0.0000 0.3921
F2 0.0000 1.6828 0.2789   1.6828 0.0000 0.2789
F3 0.0000 -1.6828 0.2789   -1.6828 0.0000 0.2789
F4 1.2509 0.0000 -0.6275   0.0000 1.2509 -0.6275
F5 -1.2509 0.0000 -0.6275   0.0000 -1.2509 -0.6275
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5
S1 1.6866 1.6866 1.6138 1.6138
F2 1.6866 3.3656 2.2843 2.2843
F3 1.6866 3.3656 2.2843 2.2843
F4 1.6138 2.2843 2.2843 2.5018
F5 1.6138 2.2843 2.2843 2.5018
Maximum atom distance is 3.3656Å between atoms F2 and F3.
picture of Sulfur tetrafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 172.307 F2 S1 F4 87.571
F2 S1 F5 87.571 F3 S1 F4 87.571
F3 S1 F5 87.571 F4 S1 F5 101.637

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.