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Geometry for S2F10 (disulphur decafluoride) 1A1 D4D

1910171554
InChI=1S/F10S2/c1-11(2,3,4,5)12(6,7,8,9)10 INChIKey=

PBEPBEultrafine/6-31G*


Point group is D4d
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 1.1660   1.1660 0.0000 0.0000
S2 0.0000 0.0000 -1.1660   -1.1660 0.0000 0.0000
F3 0.0000 1.6326 1.1657   1.1657 1.6326 0.0000
F4 -1.6326 0.0000 1.1657   1.1657 0.0000 -1.6326
F5 0.0000 -1.6326 1.1657   1.1657 -1.6326 0.0000
F6 1.6326 0.0000 1.1657   1.1657 0.0000 1.6326
F7 0.0000 0.0000 2.7786   2.7786 0.0000 0.0000
F8 1.1544 1.1544 -1.1657   -1.1657 1.1544 1.1544
F9 1.1544 -1.1544 -1.1657   -1.1657 -1.1544 1.1544
F10 -1.1544 -1.1544 -1.1657   -1.1657 -1.1544 -1.1544
F11 -1.1544 1.1544 -1.1657   -1.1657 1.1544 -1.1544
F12 0.0000 0.0000 -2.7786   -2.7786 0.0000 0.0000
Atom - Atom Distances (Å)
  S1 S2 F3 F4 F5 F6 F7 F8 F9 F10 F11 F12
S1 2.3320 1.6326 1.6326 1.6326 1.6326 1.6126 2.8465 2.8465 2.8465 2.8465 3.9446
S2 2.3320 2.8465 2.8465 2.8465 2.8465 3.9446 1.6326 1.6326 1.6326 1.6326 1.6126
F3 1.6326 2.8465 2.3089 3.2652 2.3089 2.2949 2.6452 3.8126 3.8126 2.6452 4.2688
F4 1.6326 2.8465 2.3089 2.3089 3.2652 2.2949 3.8126 3.8126 2.6452 2.6452 4.2688
F5 1.6326 2.8465 3.2652 2.3089 2.3089 2.2949 3.8126 2.6452 2.6452 3.8126 4.2688
F6 1.6326 2.8465 2.3089 3.2652 2.3089 2.2949 2.6452 2.6452 3.8126 3.8126 4.2688
F7 1.6126 3.9446 2.2949 2.2949 2.2949 2.2949 4.2688 4.2688 4.2688 4.2688 5.5571
F8 2.8465 1.6326 2.6452 3.8126 3.8126 2.6452 4.2688 2.3089 3.2652 2.3089 2.2949
F9 2.8465 1.6326 3.8126 3.8126 2.6452 2.6452 4.2688 2.3089 2.3089 3.2652 2.2949
F10 2.8465 1.6326 3.8126 2.6452 2.6452 3.8126 4.2688 3.2652 2.3089 2.3089 2.2949
F11 2.8465 1.6326 2.6452 2.6452 3.8126 3.8126 4.2688 2.3089 3.2652 2.3089 2.2949
F12 3.9446 1.6126 4.2688 4.2688 4.2688 4.2688 5.5571 2.2949 2.2949 2.2949 2.2949
Maximum atom distance is 5.5571Å between atoms F7 and F12.
picture of disulphur decafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S1 S2 F8 89.991 S1 S2 F9 89.991
S1 S2 F10 89.991 S1 S2 F11 89.991
S1 S2 F12 180.000 S2 S1 F3 89.991
S2 S1 F4 89.991 S2 S1 F5 89.991
S2 S1 F6 89.991 S2 S1 F7 180.000
F3 S1 F4 90.000 F3 S1 F5 179.981
F3 S1 F6 90.000 F3 S1 F7 90.009
F4 S1 F5 90.000 F4 S1 F6 179.981
F4 S1 F7 90.009 F5 S1 F6 90.000
F5 S1 F7 90.009 F6 S1 F7 90.009
F8 S2 F9 90.000 F8 S2 F10 179.981
F8 S2 F11 90.000 F8 S2 F12 90.009
F9 S2 F10 90.000 F9 S2 F11 179.981
F9 S2 F12 90.009 F10 S2 F11 90.000
F10 S2 F12 90.009 F11 S2 F12 90.009

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.