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Geometry for SiH(CH3)3 (trimethylsilane) 1A1 C3V

1910171554
InChI=1S/C3H10Si/c1-4(2)3/h4H,1-3H3 INChIKey=PQDJYEQOELDLCP-UHFFFAOYSA-N

wB97X-D/6-31G*


Point group is C3v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.3269   0.0000 0.0000 0.3269
H2 0.0000 0.0000 1.8392   0.0000 0.0000 1.8392
C3 0.0000 1.5460 -0.1996   1.1998 0.9750 -0.1996
C4 1.3389 -0.7730 -0.1996   -1.4443 0.5516 -0.1996
C5 -1.3389 -0.7730 -0.1996   0.2445 -1.5266 -0.1996
H6 0.0000 1.5600 -1.2423   1.2107 0.9838 -1.2423
H7 1.3510 -0.7800 -1.2423   -1.4573 0.5565 -1.2423
H8 -1.3510 -0.7800 -1.2423   0.2467 -1.5404 -1.2423
H9 -0.8540 2.0451 0.1508   2.1257 0.6270 0.1508
H10 0.8540 2.0451 0.1508   1.0485 1.9525 0.1508
H11 2.1981 -0.2829 0.1508   -1.6058 1.5274 0.1508
H12 1.3441 -1.7621 0.1508   -2.2152 -0.0682 0.1508
H13 -1.3441 -1.7621 0.1508   -0.5199 -2.1544 0.1508
H14 -2.1981 -0.2829 0.1508   1.1667 -1.8843 0.1508
Atom - Atom Distances (Å)
  Si1 H2 C3 C4 C5 H6 H7 H8 H9 H10 H11 H12 H13 H14
Si1 1.5123 1.6332 1.6332 1.6332 2.2126 2.2126 2.2126 2.2232 2.2232 2.2232 2.2232 2.2232 2.2232
H2 1.5123 2.5587 2.5587 2.5587 3.4538 3.4538 3.4538 2.7861 2.7861 2.7861 2.7861 2.7861 2.7861
C3 1.6332 2.5587 2.6778 2.6778 1.0427 2.8849 2.8849 1.0494 1.0494 2.8809 3.5879 3.5879 2.8809
C4 1.6332 2.5587 2.6778 2.6778 2.8849 1.0427 2.8849 3.5879 2.8809 1.0494 1.0494 2.8809 3.5879
C5 1.6332 2.5587 2.6778 2.6778 2.8849 2.8849 1.0427 2.8809 3.5879 3.5879 2.8809 1.0494 1.0494
H6 2.2126 3.4538 1.0427 2.8849 2.8849 2.7020 2.7020 1.7045 1.7045 3.1888 3.8450 3.8450 3.1888
H7 2.2126 3.4538 2.8849 1.0427 2.8849 2.7020 2.7020 3.8450 3.1888 1.7045 1.7045 3.1888 3.8450
H8 2.2126 3.4538 2.8849 2.8849 1.0427 2.7020 2.7020 3.1888 3.8450 3.8450 3.1888 1.7045 1.7045
H9 2.2232 2.7861 1.0494 3.5879 2.8809 1.7045 3.8450 3.1888 1.7080 3.8386 4.3962 3.8386 2.6882
H10 2.2232 2.7861 1.0494 2.8809 3.5879 1.7045 3.1888 3.8450 1.7080 2.6882 3.8386 4.3962 3.8386
H11 2.2232 2.7861 2.8809 1.0494 3.5879 3.1888 1.7045 3.8450 3.8386 2.6882 1.7080 3.8386 4.3962
H12 2.2232 2.7861 3.5879 1.0494 2.8809 3.8450 1.7045 3.1888 4.3962 3.8386 1.7080 2.6882 3.8386
H13 2.2232 2.7861 3.5879 2.8809 1.0494 3.8450 3.1888 1.7045 3.8386 4.3962 3.8386 2.6882 1.7080
H14 2.2232 2.7861 2.8809 3.5879 1.0494 3.1888 3.8450 1.7045 2.6882 3.8386 4.3962 3.8386 1.7080
Maximum atom distance is 4.3962Å between atoms H9 and H12.
picture of trimethylsilane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
C3 Si1 C4 110.128 C3 Si1 C5 110.128
C4 Si1 C5 110.128
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Si1 C3 H6 109.574 Si1 C3 H9 110.031
Si1 C3 H10 110.031 Si1 C4 H7 109.574
Si1 C4 H11 110.031 Si1 C4 H12 110.031
Si1 C5 H8 109.574 Si1 C5 H13 110.031
Si1 C5 H14 110.031 H2 Si1 C3 108.806
H2 Si1 C4 108.806 H2 Si1 C5 108.806
H6 C3 H9 109.119 H6 C3 H10 109.119
H7 C4 H11 109.119 H7 C4 H12 109.119
H8 C5 H13 109.119 H8 C5 H14 109.119
H9 C3 H10 108.943 H11 C4 H12 108.943
H13 C5 H14 108.943

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.