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Geometry for Si3H8 (trisilane) 1A1 C2V

1910171554
InChI=1S/H8Si3/c1-3-2/h3H2,1-2H3 INChIKey=VEDJZFSRVVQBIL-UHFFFAOYSA-N

B1B95/6-31G*


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.8807   0.8807 0.0000 0.0000
Si2 0.0000 1.9398 -0.4147   -0.4147 0.0000 1.9398
Si3 0.0000 -1.9398 -0.4147   -0.4147 0.0000 -1.9398
H4 1.1987 0.0000 1.7642   1.7642 1.1987 0.0000
H5 -1.1987 0.0000 1.7642   1.7642 -1.1987 0.0000
H6 0.0000 3.1515 0.4459   0.4459 0.0000 3.1515
H7 0.0000 -3.1515 0.4459   0.4459 0.0000 -3.1515
H8 1.2041 1.9819 -1.2848   -1.2848 1.2041 1.9819
H9 -1.2041 1.9819 -1.2848   -1.2848 -1.2041 1.9819
H10 -1.2041 -1.9819 -1.2848   -1.2848 -1.2041 -1.9819
H11 1.2041 -1.9819 -1.2848   -1.2848 1.2041 -1.9819
Atom - Atom Distances (Å)
  Si1 Si2 Si3 H4 H5 H6 H7 H8 H9 H10 H11
Si1 2.3325 2.3325 1.4891 1.4891 3.1813 3.1813 3.1729 3.1729 3.1729 3.1729
Si2 2.3325 3.8796 3.1539 3.1539 1.4862 5.1635 1.4862 1.4862 4.1937 4.1937
Si3 2.3325 3.8796 3.1539 3.1539 5.1635 1.4862 4.1937 4.1937 1.4862 1.4862
H4 1.4891 3.1539 3.1539 2.3975 3.6203 3.6203 3.6365 4.3586 4.3586 3.6365
H5 1.4891 3.1539 3.1539 2.3975 3.6203 3.6203 4.3586 3.6365 3.6365 4.3586
H6 3.1813 1.4862 5.1635 3.6203 3.6203 6.3030 2.4110 2.4110 5.5495 5.5495
H7 3.1813 5.1635 1.4862 3.6203 3.6203 6.3030 5.5495 5.5495 2.4110 2.4110
H8 3.1729 1.4862 4.1937 3.6365 4.3586 2.4110 5.5495 2.4081 4.6380 3.9638
H9 3.1729 1.4862 4.1937 4.3586 3.6365 2.4110 5.5495 2.4081 3.9638 4.6380
H10 3.1729 4.1937 1.4862 4.3586 3.6365 5.5495 2.4110 4.6380 3.9638 2.4081
H11 3.1729 4.1937 1.4862 3.6365 4.3586 5.5495 2.4110 3.9638 4.6380 2.4081
Maximum atom distance is 6.3030Å between atoms H6 and H7.
picture of trisilane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S2 S1 S3 112.533
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S1 S2 H6 110.883 S1 S2 H8 110.409
S1 S2 H9 110.409 S1 S3 H7 110.883
S1 S3 H10 110.409 S1 S3 H11 110.409
S2 S1 H4 109.237 S2 S1 H5 109.237
S3 S1 H4 109.237 S3 S1 H5 109.237
H4 S1 H5 107.218 H6 S2 H8 108.417
H6 S2 H9 108.417 H7 S3 H10 108.417
H7 S3 H11 108.417 H8 S2 H9 108.226
H10 S3 H11 108.226

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.