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Geometry for SF4 (Sulfur tetrafluoride) 1A1 C2V

1910171554
InChI=1S/F4S/c1-5(2,3)4 INChIKey=QHMQWEPBXSHHLH-UHFFFAOYSA-N

B3LYP/6-31G*


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.3903   0.0000 0.0000 0.3903
F2 0.0000 1.6683 0.2674   1.6683 0.0000 0.2674
F3 0.0000 -1.6683 0.2674   -1.6683 0.0000 0.2674
F4 1.2377 0.0000 -0.6144   0.0000 1.2377 -0.6144
F5 -1.2377 0.0000 -0.6144   0.0000 -1.2377 -0.6144
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5
S1 1.6728 1.6728 1.5941 1.5941
F2 1.6728 3.3366 2.2567 2.2567
F3 1.6728 3.3366 2.2567 2.2567
F4 1.5941 2.2567 2.2567 2.4754
F5 1.5941 2.2567 2.2567 2.4754
Maximum atom distance is 3.3366Å between atoms F2 and F3.
picture of Sulfur tetrafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 171.573 F2 S1 F4 87.346
F2 S1 F5 87.346 F3 S1 F4 87.346
F3 S1 F5 87.346 F4 S1 F5 101.863

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.