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Geometry for SF5Cl (sulfur chloropentafluoride) 1A1 C4V

1910171554
InChI=1S/ClF5S/c1-7(2,3,4,5)6 INChIKey=GSYNTTDHMKSMFY-UHFFFAOYSA-N

HF/CEP-31G


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 -0.2602   -0.2602 0.0000 0.0000
Cl2 0.0000 0.0000 1.9578   1.9578 0.0000 0.0000
F3 0.0000 1.7231 -0.3155   -0.3155 1.7231 0.0000
F4 1.7231 0.0000 -0.3155   -0.3155 0.0000 1.7231
F5 0.0000 -1.7231 -0.3155   -0.3155 -1.7231 0.0000
F6 -1.7231 0.0000 -0.3155   -0.3155 0.0000 -1.7231
F7 0.0000 0.0000 -1.9733   -1.9733 0.0000 0.0000
Atom - Atom Distances (Å)
  S1 Cl2 F3 F4 F5 F6 F7
S1 2.2180 1.7240 1.7240 1.7240 1.7240 1.7131
Cl2 2.2180 2.8525 2.8525 2.8525 2.8525 3.9311
F3 1.7240 2.8525 2.4368 3.4461 2.4368 2.3911
F4 1.7240 2.8525 2.4368 2.4368 3.4461 2.3911
F5 1.7240 2.8525 3.4461 2.4368 2.4368 2.3911
F6 1.7240 2.8525 2.4368 3.4461 2.4368 2.3911
F7 1.7131 3.9311 2.3911 2.3911 2.3911 2.3911
Maximum atom distance is 3.9311Å between atoms Cl2 and F7.
picture of sulfur chloropentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl2 S1 F3 91.838 Cl2 S1 F4 91.838
Cl2 S1 F5 91.838 Cl2 S1 F6 91.838
Cl2 S1 F7 180.000 F3 S1 F4 89.941
F3 S1 F5 176.323 F3 S1 F6 89.941
F3 S1 F7 88.162 F4 S1 F5 89.941
F4 S1 F6 176.323 F4 S1 F7 88.162
F5 S1 F6 89.941 F5 S1 F7 88.162
F6 S1 F7 88.162

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.