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Geometry for C6H6 (Trimethylenecycopropane) 1A' D3H

1910171554
InChI=1S/C6H6/c1-4-5(2)6(4)3/h1-3H2 INChIKey=UPWZWQGQRNPKTE-UHFFFAOYSA-N

HF/CEP-31G*


Point group is D3h
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
C1 0.0000 0.8465 0.0000   -0.5133 0.6731 0.0000
C2 0.7331 -0.4232 0.0000   0.8396 0.1080 0.0000
C3 -0.7331 -0.4232 0.0000   -0.3263 -0.7811 0.0000
C4 0.0000 2.1931 0.0000   -1.3298 1.7439 0.0000
C5 1.8993 -1.0966 0.0000   2.1752 0.2797 0.0000
C6 -1.8993 -1.0966 0.0000   -0.8454 -2.0236 0.0000
H7 -0.9282 2.7481 0.0000   -2.4045 1.6224 0.0000
H8 0.9282 2.7481 0.0000   -0.9282 2.7481 0.0000
H9 2.8440 -0.5702 0.0000   2.6073 1.2711 0.0000
H10 1.9158 -2.1779 0.0000   2.8440 -0.5702 0.0000
H11 -1.9158 -2.1779 0.0000   -0.2028 -2.8935 0.0000
H12 -2.8440 -0.5702 0.0000   -1.9158 -2.1779 0.0000
Atom - Atom Distances (Å)
  C1 C2 C3 C4 C5 C6 H7 H8 H9 H10 H11 H12
C1 1.4662 1.4662 1.3466 2.7171 2.7171 2.1161 2.1161 3.1774 3.5801 3.5801 3.1774
C2 1.4662 1.4662 2.7171 1.3466 2.7171 3.5801 3.1774 2.1161 2.1161 3.1774 3.5801
C3 1.4662 1.4662 2.7171 2.7171 1.3466 3.1774 3.5801 3.5801 3.1774 2.1161 2.1161
C4 1.3466 2.7171 2.7171 3.7986 3.7986 1.0815 1.0815 3.9654 4.7725 4.7725 3.9654
C5 2.7171 1.3466 2.7171 3.7986 3.7986 4.7725 3.9654 1.0815 1.0815 3.9654 4.7725
C6 2.7171 2.7171 1.3466 3.7986 3.7986 3.9654 4.7725 4.7725 3.9654 1.0815 1.0815
H7 2.1161 3.5801 3.1774 1.0815 4.7725 3.9654 1.8565 5.0241 5.6881 5.0241 3.8316
H8 2.1161 3.1774 3.5801 1.0815 3.9654 4.7725 1.8565 3.8316 5.0241 5.6881 5.0241
H9 3.1774 2.1161 3.5801 3.9654 1.0815 4.7725 5.0241 3.8316 1.8565 5.0241 5.6881
H10 3.5801 2.1161 3.1774 4.7725 1.0815 3.9654 5.6881 5.0241 1.8565 3.8316 5.0241
H11 3.5801 3.1774 2.1161 4.7725 3.9654 1.0815 5.0241 5.6881 5.0241 3.8316 1.8565
H12 3.1774 3.5801 2.1161 3.9654 4.7725 1.0815 3.8316 5.0241 5.6881 5.0241 1.8565
Maximum atom distance is 5.6881Å between atoms H7 and H10.
picture of Trimethylenecycopropane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
C1 C2 C3 60.000 C1 C2 C5 150.000
C1 C3 C2 60.000 C1 C3 C6 150.000
C2 C1 C3 60.000 C2 C1 C4 150.000
C2 C3 C6 150.000 C3 C1 C4 150.000
C3 C2 C5 150.000
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
C1 C4 H7 120.875 C1 C4 H8 120.875
C2 C5 H9 120.875 C2 C5 H10 120.875
C3 C6 H11 120.875 C3 C6 H12 120.875
H7 C4 H8 118.249 H9 C5 H10 118.249
H11 C6 H12 118.249

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.