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Geometry for Si3H8 (trisilane) 1A1 C2V

1910171554
InChI=1S/H8Si3/c1-3-2/h3H2,1-2H3 INChIKey=VEDJZFSRVVQBIL-UHFFFAOYSA-N

HF/LANL2DZ


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.8802   0.8802 0.0000 0.0000
Si2 0.0000 1.9492 -0.4150   -0.4150 0.0000 1.9492
Si3 0.0000 -1.9492 -0.4150   -0.4150 0.0000 -1.9492
H4 1.1918 0.0000 1.7506   1.7506 1.1918 0.0000
H5 -1.1918 0.0000 1.7506   1.7506 -1.1918 0.0000
H6 0.0000 3.1436 0.4493   0.4493 0.0000 3.1436
H7 0.0000 -3.1436 0.4493   0.4493 0.0000 -3.1436
H8 1.1969 1.9830 -1.2756   -1.2756 1.1969 1.9830
H9 -1.1969 1.9830 -1.2756   -1.2756 -1.1969 1.9830
H10 -1.1969 -1.9830 -1.2756   -1.2756 -1.1969 -1.9830
H11 1.1969 -1.9830 -1.2756   -1.2756 1.1969 -1.9830
Atom - Atom Distances (Å)
  Si1 Si2 Si3 H4 H5 H6 H7 H8 H9 H10 H11
Si1 2.3402 2.3402 1.4758 1.4758 3.1730 3.1730 3.1642 3.1642 3.1642 3.1642
Si2 2.3402 3.8983 3.1479 3.1479 1.4743 5.1655 1.4746 1.4746 4.1994 4.1994
Si3 2.3402 3.8983 3.1479 3.1479 5.1655 1.4743 4.1994 4.1994 1.4746 1.4746
H4 1.4758 3.1479 3.1479 2.3835 3.6050 3.6050 3.6181 4.3354 4.3354 3.6181
H5 1.4758 3.1479 3.1479 2.3835 3.6050 3.6050 4.3354 3.6181 3.6181 4.3354
H6 3.1730 1.4743 5.1655 3.6050 3.6050 6.2871 2.3989 2.3989 5.5398 5.5398
H7 3.1730 5.1655 1.4743 3.6050 3.6050 6.2871 5.5398 5.5398 2.3989 2.3989
H8 3.1642 1.4746 4.1994 3.6181 4.3354 2.3989 5.5398 2.3938 4.6325 3.9661
H9 3.1642 1.4746 4.1994 4.3354 3.6181 2.3989 5.5398 2.3938 3.9661 4.6325
H10 3.1642 4.1994 1.4746 4.3354 3.6181 5.5398 2.3989 4.6325 3.9661 2.3938
H11 3.1642 4.1994 1.4746 3.6181 4.3354 5.5398 2.3989 3.9661 4.6325 2.3938
Maximum atom distance is 6.2871Å between atoms H6 and H7.
picture of trisilane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S2 S1 S3 112.795
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S1 S2 H6 110.508 S1 S2 H8 110.008
S1 S2 H9 110.008 S1 S3 H7 110.508
S1 S3 H10 110.008 S1 S3 H11 110.008
S2 S1 H4 109.052 S2 S1 H5 109.052
S3 S1 H4 109.052 S3 S1 H5 109.052
H4 S1 H5 107.712 H6 S2 H8 108.877
H6 S2 H9 108.877 H7 S3 H10 108.877
H7 S3 H11 108.877 H8 S2 H9 108.521
H10 S3 H11 108.521

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.