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Geometry for N(CH3)3 (Trimethylamine) 1A1 C3V

1910171554
InChI=1S/C3H9N/c1-4(2)3/h1-3H3 INChIKey=GETQZCLCWQTVFV-UHFFFAOYSA-N

HF/SDD


Point group is C3v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
N1 0.0000 0.0000 0.3217   0.0000 0.0000 0.3217
C2 0.0000 1.4119 -0.0538   -0.6169 1.2700 -0.0538
C3 1.2228 -0.7060 -0.0538   1.4083 -0.1007 -0.0538
C4 -1.2228 -0.7060 -0.0538   -0.7914 -1.1693 -0.0538
H5 0.0000 1.5631 -1.1382   -0.6830 1.4060 -1.1382
H6 1.3537 -0.7816 -1.1382   1.5591 -0.1115 -1.1382
H7 -1.3537 -0.7816 -1.1382   -0.8761 -1.2945 -1.1382
H8 -0.8758 1.8999 0.3553   -1.6179 1.3262 0.3553
H9 0.8758 1.8999 0.3553   -0.0424 2.0916 0.3553
H10 2.0833 -0.1915 0.3553   1.9575 0.7381 0.3553
H11 1.2074 -1.7084 0.3553   1.8326 -1.0091 0.3553
H12 -1.2074 -1.7084 0.3553   -0.3396 -2.0643 0.3553
H13 -2.0833 -0.1915 0.3553   -1.7902 -1.0825 0.3553
X14 0.0000 0.0000 1.3217   0.0000 0.0000 1.3217
Atom - Atom Distances (Å)
  N1 C2 C3 C4 H5 H6 H7 H8 H9 H10 H11 H12 H13 X14
N1 1.4610 1.4610 1.4610 2.1389 2.1389 2.1389 2.0923 2.0923 2.0923 2.0923 2.0923 2.0923 1.0000
C2 1.4610 2.4455 2.4455 1.0949 2.7964 2.7964 1.0828 1.0828 2.6605 3.3707 3.3707 2.6605 1.9712
C3 1.4610 2.4455 2.4456 2.7964 1.0949 2.7964 3.3707 2.6605 1.0828 1.0828 2.6605 3.3707 1.9712
C4 1.4610 2.4455 2.4456 2.7964 2.7964 1.0949 2.6605 3.3707 3.3707 2.6605 1.0828 1.0828 1.9712
H5 2.1389 1.0949 2.7964 2.7964 2.7074 2.7074 1.7639 1.7639 3.1063 3.7936 3.7936 3.1063 2.9146
H6 2.1389 2.7964 1.0949 2.7964 2.7074 2.7074 3.7936 3.1063 1.7639 1.7639 3.1063 3.7936 2.9146
H7 2.1389 2.7964 2.7964 1.0949 2.7074 2.7074 3.1063 3.7936 3.7936 3.1063 1.7639 1.7639 2.9146
H8 2.0923 1.0828 3.3707 2.6605 1.7639 3.7936 3.1063 1.7516 3.6235 4.1665 3.6235 2.4149 2.3045
H9 2.0923 1.0828 2.6605 3.3707 1.7639 3.1063 3.7936 1.7516 2.4149 3.6235 4.1665 3.6235 2.3045
H10 2.0923 2.6605 1.0828 3.3707 3.1063 1.7639 3.7936 3.6235 2.4149 1.7516 3.6235 4.1665 2.3045
H11 2.0923 3.3707 1.0828 2.6605 3.7936 1.7639 3.1063 4.1665 3.6235 1.7516 2.4149 3.6235 2.3045
H12 2.0923 3.3707 2.6605 1.0828 3.7936 3.1063 1.7639 3.6235 4.1665 3.6235 2.4149 1.7516 2.3045
H13 2.0923 2.6605 3.3707 1.0828 3.1063 3.7936 1.7639 2.4149 3.6235 4.1665 3.6235 1.7516 2.3045
X14 1.0000 1.9712 1.9712 1.9712 2.9146 2.9146 2.9146 2.3045 2.3045 2.3045 2.3045 2.3045 2.3045
Maximum atom distance is 4.1665Å between atoms H10 and H13.
picture of Trimethylamine
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
C2 N1 C3 113.633 C2 N1 C4 113.633
C2 N1 X14 104.895 C3 N1 C4 113.634
C3 N1 X14 104.895 C4 N1 X14 104.895
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
N1 C2 H5 112.831 N1 C2 H8 109.776
N1 C2 H9 109.776 N1 C3 H6 112.831
N1 C3 H10 109.776 N1 C3 H11 109.776
N1 C4 H7 112.831 N1 C4 H12 109.776
N1 C4 H13 109.776 H5 C2 H8 108.182
H5 C2 H9 108.182 H6 C3 H10 108.182
H6 C3 H11 108.182 H7 C4 H12 108.182
H7 C4 H13 108.182 H8 C2 H9 107.958
H10 C3 H11 107.958 H12 C4 H13 107.958

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.