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Geometry for AsF5 (Arsenic pentafluoride) 1A1' D3H

1910171554
InChI=1S/AsF5/c2-1(3,4,5)6 INChIKey=YBGKQGSCGDNZIB-UHFFFAOYSA-N

B1B95/aug-cc-pVDZ


Point group is D3h
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
As1 0.0000 0.0000 0.0000   0.0000 0.0000 0.0000
F2 0.0000 1.6983 0.0000   1.6983 0.0000 0.0000
F3 1.4708 -0.8491 0.0000   -0.8491 0.0000 1.4708
F4 -1.4708 -0.8491 0.0000   -0.8491 0.0000 -1.4708
F5 0.0000 0.0000 1.7189   0.0000 1.7189 0.0000
F6 0.0000 0.0000 -1.7189   0.0000 -1.7189 0.0000
Atom - Atom Distances (Å)
  As1 F2 F3 F4 F5 F6
As1 1.6983 1.6983 1.6983 1.7189 1.7189
F2 1.6983 2.9415 2.9415 2.4164 2.4164
F3 1.6983 2.9415 2.9415 2.4164 2.4164
F4 1.6983 2.9415 2.9415 2.4164 2.4164
F5 1.7189 2.4164 2.4164 2.4164 3.4378
F6 1.7189 2.4164 2.4164 2.4164 3.4378
Maximum atom distance is 3.4378Å between atoms F5 and F6.
picture of Arsenic pentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 As1 F3 120.000 F2 As1 F4 120.000
F2 As1 F5 90.000 F2 As1 F6 90.000
F3 As1 F4 120.000 F3 As1 F5 90.000
F3 As1 F6 90.000 F4 As1 F5 90.000
F4 As1 F6 90.000 F5 As1 F6 180.000

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.