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Geometry for Si3H8 (trisilane) 1A1 C2V

1910171554
InChI=1S/H8Si3/c1-3-2/h3H2,1-2H3 INChIKey=VEDJZFSRVVQBIL-UHFFFAOYSA-N

HF/aug-cc-pVTZ


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.8987   0.8987 0.0000 0.0000
Si2 0.0000 1.9686 -0.4231   -0.4231 0.0000 1.9686
Si3 0.0000 -1.9686 -0.4231   -0.4231 0.0000 -1.9686
H4 1.1993 0.0000 1.7734   1.7734 1.1993 0.0000
H5 -1.1993 0.0000 1.7734   1.7734 -1.1993 0.0000
H6 0.0000 3.1749 0.4358   0.4358 0.0000 3.1749
H7 0.0000 -3.1749 0.4358   0.4358 0.0000 -3.1749
H8 1.2020 2.0041 -1.2882   -1.2882 1.2020 2.0041
H9 -1.2020 2.0041 -1.2882   -1.2882 -1.2020 2.0041
H10 -1.2020 -2.0041 -1.2882   -1.2882 -1.2020 -2.0041
H11 1.2020 -2.0041 -1.2882   -1.2882 1.2020 -2.0041
Atom - Atom Distances (Å)
  Si1 Si2 Si3 H4 H5 H6 H7 H8 H9 H10 H11
Si1 2.3712 2.3712 1.4844 1.4844 3.2084 3.2084 3.2006 3.2006 3.2006 3.2006
Si2 2.3712 3.9373 3.1841 3.1841 1.4808 5.2147 1.4814 1.4814 4.2398 4.2398
Si3 2.3712 3.9373 3.1841 3.1841 5.2147 1.4808 4.2398 4.2398 1.4814 1.4814
H4 1.4844 3.1841 3.1841 2.3985 3.6479 3.6479 3.6592 4.3768 4.3768 3.6592
H5 1.4844 3.1841 3.1841 2.3985 3.6479 3.6479 4.3768 3.6592 3.6592 4.3768
H6 3.2084 1.4808 5.2147 3.6479 3.6479 6.3497 2.4058 2.4058 5.5891 5.5891
H7 3.2084 5.2147 1.4808 3.6479 3.6479 6.3497 5.5891 5.5891 2.4058 2.4058
H8 3.2006 1.4814 4.2398 3.6592 4.3768 2.4058 5.5891 2.4040 4.6738 4.0081
H9 3.2006 1.4814 4.2398 4.3768 3.6592 2.4058 5.5891 2.4040 4.0081 4.6738
H10 3.2006 4.2398 1.4814 4.3768 3.6592 5.5891 2.4058 4.6738 4.0081 2.4040
H11 3.2006 4.2398 1.4814 3.6592 4.3768 5.5891 2.4058 4.0081 4.6738 2.4040
Maximum atom distance is 6.3497Å between atoms H6 and H7.
picture of trisilane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S2 S1 S3 112.242
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S1 S2 H6 110.666 S1 S2 H8 110.206
S1 S2 H9 110.206 S1 S3 H7 110.666
S1 S3 H10 110.206 S1 S3 H11 110.206
S2 S1 H4 109.177 S2 S1 H5 109.177
S3 S1 H4 109.177 S3 S1 H5 109.177
H4 S1 H5 107.787 H6 S2 H8 108.619
H6 S2 H9 108.619 H7 S3 H10 108.619
H7 S3 H11 108.619 H8 S2 H9 108.467
H10 S3 H11 108.467

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.