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Geometry for AsF5 (Arsenic pentafluoride) 1A1' D3H

1910171554
InChI=1S/AsF5/c2-1(3,4,5)6 INChIKey=YBGKQGSCGDNZIB-UHFFFAOYSA-N

B97D3/aug-cc-pVTZ


Point group is D3h
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
As1 0.0000 0.0000 0.0000   0.0000 0.0000 0.0000
F2 0.0000 1.7057 0.0000   0.0000 1.2061 -1.2061
F3 1.4772 -0.8528 0.0000   0.0000 0.4415 1.6476
F4 -1.4772 -0.8528 0.0000   0.0000 -1.6476 -0.4415
F5 0.0000 0.0000 1.7278   1.7278 0.0000 0.0000
F6 0.0000 0.0000 -1.7278   -1.7278 0.0000 0.0000
Atom - Atom Distances (Å)
  As1 F2 F3 F4 F5 F6
As1 1.7057 1.7057 1.7057 1.7278 1.7278
F2 1.7057 2.9543 2.9543 2.4279 2.4279
F3 1.7057 2.9543 2.9543 2.4279 2.4279
F4 1.7057 2.9543 2.9543 2.4279 2.4279
F5 1.7278 2.4279 2.4279 2.4279 3.4557
F6 1.7278 2.4279 2.4279 2.4279 3.4557
Maximum atom distance is 3.4557Å between atoms F5 and F6.
picture of Arsenic pentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 As1 F3 120.000 F2 As1 F4 120.000
F2 As1 F5 90.000 F2 As1 F6 90.000
F3 As1 F4 120.000 F3 As1 F5 90.000
F3 As1 F6 90.000 F4 As1 F5 90.000
F4 As1 F6 90.000 F5 As1 F6 180.000

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.