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Geometry for AsCl3 (Arsenous trichloride) 1A1 C3V

1910171554
1S/AsCl3/c2-1(3)4 INChIKey=OEYOHULQRFXULB-UHFFFAOYSA-N

CCSD=FULL/6-31G(2df,p)


Point group is C3v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
As1 0.0000 0.0000 0.6251   0.0000 0.0000 0.6251
Cl2 0.0000 1.8779 -0.4045   1.8779 0.0000 -0.4045
Cl3 1.6263 -0.9389 -0.4045   -0.9389 1.6263 -0.4045
Cl4 -1.6263 -0.9389 -0.4045   -0.9389 -1.6263 -0.4045
Atom - Atom Distances (Å)
  As1 Cl2 Cl3 Cl4
As1 2.1416 2.1416 2.1416
Cl2 2.1416 3.2526 3.2526
Cl3 2.1416 3.2526 3.2526
Cl4 2.1416 3.2526 3.2526
Maximum atom distance is 3.2526Å between atoms Cl3 and Cl4.
picture of Arsenous trichloride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl2 As1 Cl3 98.819 Cl2 As1 Cl4 98.819
Cl3 As1 Cl4 98.819

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.