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Geometry for S2F10 (disulphur decafluoride) 1A1 D4D

1910171554
InChI=1S/F10S2/c1-11(2,3,4,5)12(6,7,8,9)10 INChIKey=

M06-2X/6-31G(2df,p)


Point group is D4d
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 1.1188   1.1188 0.0000 0.0000
S2 0.0000 0.0000 -1.1188   -1.1188 0.0000 0.0000
F3 0.0000 1.5738 1.1249   1.1249 1.1954 -1.0236
F4 -1.5738 0.0000 1.1249   1.1249 -1.0236 -1.1954
F5 0.0000 -1.5738 1.1249   1.1249 -1.1954 1.0236
F6 1.5738 0.0000 1.1249   1.1249 1.0236 1.1954
F7 0.0000 0.0000 2.6769   2.6769 0.0000 0.0000
F8 1.1128 1.1128 -1.1249   -1.1249 1.5691 0.1215
F9 1.1128 -1.1128 -1.1249   -1.1249 -0.1215 1.5691
F10 -1.1128 -1.1128 -1.1249   -1.1249 -1.5691 -0.1215
F11 -1.1128 1.1128 -1.1249   -1.1249 0.1215 -1.5691
F12 0.0000 0.0000 -2.6769   -2.6769 0.0000 0.0000
Atom - Atom Distances (Å)
  S1 S2 F3 F4 F5 F6 F7 F8 F9 F10 F11 F12
S1 2.2375 1.5738 1.5738 1.5738 1.5738 1.5582 2.7406 2.7406 2.7406 2.7406 3.7957
S2 2.2375 2.7406 2.7406 2.7406 2.7406 3.7957 1.5738 1.5738 1.5738 1.5738 1.5582
F3 1.5738 2.7406 2.2256 3.1475 2.2256 2.2103 2.5519 3.6766 3.6766 2.5519 4.1147
F4 1.5738 2.7406 2.2256 2.2256 3.1475 2.2103 3.6766 3.6766 2.5519 2.5519 4.1147
F5 1.5738 2.7406 3.1475 2.2256 2.2256 2.2103 3.6766 2.5519 2.5519 3.6766 4.1147
F6 1.5738 2.7406 2.2256 3.1475 2.2256 2.2103 2.5519 2.5519 3.6766 3.6766 4.1147
F7 1.5582 3.7957 2.2103 2.2103 2.2103 2.2103 4.1147 4.1147 4.1147 4.1147 5.3539
F8 2.7406 1.5738 2.5519 3.6766 3.6766 2.5519 4.1147 2.2256 3.1475 2.2256 2.2103
F9 2.7406 1.5738 3.6766 3.6766 2.5519 2.5519 4.1147 2.2256 2.2256 3.1475 2.2103
F10 2.7406 1.5738 3.6766 2.5519 2.5519 3.6766 4.1147 3.1475 2.2256 2.2256 2.2103
F11 2.7406 1.5738 2.5519 2.5519 3.6766 3.6766 4.1147 2.2256 3.1475 2.2256 2.2103
F12 3.7957 1.5582 4.1147 4.1147 4.1147 4.1147 5.3539 2.2103 2.2103 2.2103 2.2103
Maximum atom distance is 5.3539Å between atoms F7 and F12.
picture of disulphur decafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
S1 S2 F8 90.223 S1 S2 F9 90.223
S1 S2 F10 90.223 S1 S2 F11 90.223
S1 S2 F12 180.000 S2 S1 F3 90.223
S2 S1 F4 90.223 S2 S1 F5 90.223
S2 S1 F6 90.223 S2 S1 F7 180.000
F3 S1 F4 89.999 F3 S1 F5 179.554
F3 S1 F6 89.999 F3 S1 F7 89.777
F4 S1 F5 89.999 F4 S1 F6 179.554
F4 S1 F7 89.777 F5 S1 F6 89.999
F5 S1 F7 89.777 F6 S1 F7 89.777
F8 S2 F9 89.999 F8 S2 F10 179.554
F8 S2 F11 89.999 F8 S2 F12 89.777
F9 S2 F10 89.999 F9 S2 F11 179.554
F9 S2 F12 89.777 F10 S2 F11 89.999
F10 S2 F12 89.777 F11 S2 F12 89.777

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.