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Geometry for CH3NHNHCH3 (dimethyl hydrazine) 1A C2

1910171554
InChI=1S/C2H8N2/c1-3-4-2/h3-4H,1-2H3 INChIKey=DIIIISSCIXVANO-UHFFFAOYSA-N

B3LYP/6-31G(2df,p)


Point group is C2
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
N1 -0.1618 0.6924 -0.6801   -0.6857 0.1363 0.6924
N2 0.1618 -0.6924 -0.6801   -0.6736 -0.1870 -0.6924
C3 0.1618 1.4527 0.5256   0.5313 -0.1420 1.4527
C4 -0.1618 -1.4527 0.5256   0.5192 0.1813 -1.4527
H5 -1.1518 0.7659 -0.8879   -0.9302 1.1178 0.7659
H6 1.1518 -0.7659 -0.8879   -0.8442 -1.1841 -0.7659
H7 -0.1309 2.4940 0.3575   0.3524 0.1441 2.4940
H8 -0.3244 1.1085 1.4521   1.4390 0.3784 1.1085
H9 1.2460 1.4330 0.6853   0.7313 -1.2195 1.4330
H10 0.1309 -2.4940 0.3575   0.3622 -0.1174 -2.4940
H11 0.3244 -1.1085 1.4521   1.4632 -0.2700 -1.1085
H12 -1.2460 -1.4330 0.6853   0.6383 1.2707 -1.4330
Atom - Atom Distances (Å)
  N1 N2 C3 C4 H5 H6 H7 H8 H9 H10 H11 H12
N1 1.4222 1.4616 2.4607 1.0142 1.9737 2.0792 2.1785 2.0963 3.3639 2.8330 2.7490
N2 1.4222 2.4607 1.4616 1.9737 1.0142 3.3639 2.8330 2.7490 2.0792 2.1785 2.0963
C3 1.4616 2.4607 2.9233 2.0481 2.8107 1.0946 1.1015 1.0961 3.9504 2.7284 3.2147
C4 2.4607 1.4616 2.9233 2.8107 2.0481 3.9504 2.7284 3.2147 1.0946 1.1015 1.0961
H5 1.0142 1.9737 2.0481 2.8107 2.7664 2.3621 2.5054 2.9443 3.7180 3.3418 2.7053
H6 1.9737 1.0142 2.8107 2.0481 2.7664 3.7180 3.3418 2.7053 2.3621 2.5054 2.9443
H7 2.0792 3.3639 1.0946 3.9504 2.3621 3.7180 1.7763 1.7689 4.9949 3.7925 4.0954
H8 2.1785 2.8330 1.1015 2.7284 2.5054 3.3418 1.7763 1.7775 3.7925 2.3099 2.8100
H9 2.0963 2.7490 1.0961 3.2147 2.9443 2.7053 1.7689 1.7775 4.0954 2.8100 3.7978
H10 3.3639 2.0792 3.9504 1.0946 3.7180 2.3621 4.9949 3.7925 4.0954 1.7763 1.7689
H11 2.8330 2.1785 2.7284 1.1015 3.3418 2.5054 3.7925 2.3099 2.8100 1.7763 1.7775
H12 2.7490 2.0963 3.2147 1.0961 2.7053 2.9443 4.0954 2.8100 3.7978 1.7689 1.7775
Maximum atom distance is 4.9949Å between atoms H7 and H10.
picture of dimethyl hydrazine
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
N1 N2 C4 117.139 N2 N1 C3 117.139
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
N1 N2 H6 107.014 N1 C3 H7 107.998
N1 C3 H8 115.697 N1 C3 H9 109.254
N2 N1 H5 107.014 N2 C4 H10 107.998
N2 C4 H11 115.697 N2 C4 H12 109.254
C3 N1 H5 110.325 C4 N2 H6 110.325
H7 C3 H8 107.964 H7 C3 H9 107.694
H8 C3 H9 107.967 H10 C4 H11 107.964
H10 C4 H12 107.694 H11 C4 H12 107.967

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.