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Geometry for AsCl3 (Arsenous trichloride) 1A1 C3V

1910171554
1S/AsCl3/c2-1(3)4 INChIKey=OEYOHULQRFXULB-UHFFFAOYSA-N

wB97X-D/6-31G(2df,p)


Point group is C3v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
As1 0.0000 0.0000 0.6229   0.0000 0.0000 0.6229
Cl2 0.0000 1.8931 -0.4030   1.8931 -0.0000 -0.4030
Cl3 1.6395 -0.9466 -0.4030   -0.9466 1.6395 -0.4030
Cl4 -1.6395 -0.9466 -0.4030   -0.9466 -1.6395 -0.4030
Atom - Atom Distances (Å)
  As1 Cl2 Cl3 Cl4
As1 2.1533 2.1533 2.1533
Cl2 2.1533 3.2790 3.2790
Cl3 2.1533 3.2790 3.2790
Cl4 2.1533 3.2790 3.2790
Maximum atom distance is 3.2790Å between atoms Cl2 and Cl3.
picture of Arsenous trichloride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl2 As1 Cl3 99.177 Cl2 As1 Cl4 99.177
Cl3 As1 Cl4 99.177

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.