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Geometry for SF5 (Sulfur pentafluoride) 2A1 C4V

1910171554
InChI=1S/F5S/c1-6(2,3,4)5 INChIKey=HAQZDUWRNKKMQY-UHFFFAOYSA-N

PBEPBE/STO-3G


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.3082   0.0000 0.0000 0.3082
F2 0.0000 0.0000 -1.4601   0.0000 0.0000 -1.4601
F3 0.0000 1.7934 0.2281   1.7934 0.0000 0.2281
F4 -1.7934 0.0000 0.2281   0.0000 -1.7934 0.2281
F5 0.0000 -1.7934 0.2281   -1.7934 0.0000 0.2281
F6 1.7934 0.0000 0.2281   0.0000 1.7934 0.2281
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5 F6
S1 1.7682 1.7952 1.7952 1.7952 1.7952
F2 1.7682 2.4629 2.4629 2.4629 2.4629
F3 1.7952 2.4629 2.5362 3.5868 2.5362
F4 1.7952 2.4629 2.5362 2.5362 3.5868
F5 1.7952 2.4629 3.5868 2.5362 2.5362
F6 1.7952 2.4629 2.5362 3.5868 2.5362
Maximum atom distance is 3.5868Å between atoms F3 and F5.
picture of Sulfur pentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 87.442 F2 S1 F4 87.442
F2 S1 F5 87.442 F2 S1 F6 87.442
F3 S1 F4 89.886 F3 S1 F5 174.884
F3 S1 F6 89.886 F4 S1 F5 89.886
F4 S1 F6 174.884 F5 S1 F6 89.886

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.