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Geometry for SF5Cl (sulfur chloropentafluoride) 1A1 C4V

1910171554
InChI=1S/ClF5S/c1-7(2,3,4,5)6 INChIKey=GSYNTTDHMKSMFY-UHFFFAOYSA-N

PBEPBE/STO-3G


Point group is C4v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 -0.3059   0.0000 -0.3059 0.0000
Cl2 0.0000 0.0000 2.0477   0.0000 2.0477 0.0000
F3 0.0000 1.7523 -0.3155   1.7523 -0.3155 0.0000
F4 1.7523 0.0000 -0.3155   0.0000 -0.3155 1.7523
F5 0.0000 -1.7523 -0.3155   -1.7523 -0.3155 0.0000
F6 -1.7523 0.0000 -0.3155   0.0000 -0.3155 -1.7523
F7 0.0000 0.0000 -2.0622   0.0000 -2.0622 0.0000
Atom - Atom Distances (Å)
  S1 Cl2 F3 F4 F5 F6 F7
S1 2.3535 1.7524 1.7524 1.7524 1.7524 1.7564
Cl2 2.3535 2.9419 2.9419 2.9419 2.9419 4.1099
F3 1.7524 2.9419 2.4782 3.5047 2.4782 2.4742
F4 1.7524 2.9419 2.4782 2.4782 3.5047 2.4742
F5 1.7524 2.9419 3.5047 2.4782 2.4782 2.4742
F6 1.7524 2.9419 2.4782 3.5047 2.4782 2.4742
F7 1.7564 4.1099 2.4742 2.4742 2.4742 2.4742
Maximum atom distance is 4.1099Å between atoms Cl2 and F7.
picture of sulfur chloropentafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Cl2 S1 F3 90.314 Cl2 S1 F4 90.314
Cl2 S1 F5 90.314 Cl2 S1 F6 90.314
Cl2 S1 F7 180.000 F3 S1 F4 89.998
F3 S1 F5 179.372 F3 S1 F6 89.998
F3 S1 F7 89.686 F4 S1 F5 89.998
F4 S1 F6 179.372 F4 S1 F7 89.686
F5 S1 F6 89.998 F5 S1 F7 89.686
F6 S1 F7 89.686

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.