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Computational Chemistry Comparison and Benchmark DataBase
Release 22 (May 2022) Standard Reference Database 101
National Institute of Standards and Technology
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You are here: Home > Geometry > Calculated > Calculated geometry OR Calculated > Geometry > Calculated geometry
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Geometry for C4H8 (cyclobutane)
1A1 D2D
1910171554
InChI=1S/C4H8/c1-2-4-3-1/h1-4H2 INChIKey=PMPVIKIVABFJJI-UHFFFAOYSA-N
HF/6-311G**
Point group is D2d
| Atom |
Internal |
|
Principal |
| x (Å) |
y (Å) |
z (Å) |
|
a (Å) |
b (Å) |
c (Å) |
| C1 |
0.0000 |
1.0784 |
0.1266 |
|
1.0784 |
0.0000 |
0.1266 |
| C2 |
0.0000 |
-1.0784 |
0.1266 |
|
-1.0784 |
0.0000 |
0.1266 |
| C3 |
-1.0784 |
0.0000 |
-0.1266 |
|
0.0000 |
-1.0784 |
-0.1266 |
| C4 |
1.0784 |
0.0000 |
-0.1266 |
|
0.0000 |
1.0784 |
-0.1266 |
| H5 |
0.0000 |
1.4071 |
1.1612 |
|
1.4071 |
0.0000 |
1.1612 |
| H6 |
0.0000 |
1.9538 |
-0.5134 |
|
1.9538 |
0.0000 |
-0.5134 |
| H7 |
0.0000 |
-1.4071 |
1.1612 |
|
-1.4071 |
0.0000 |
1.1612 |
| H8 |
0.0000 |
-1.9538 |
-0.5134 |
|
-1.9538 |
0.0000 |
-0.5134 |
| H9 |
-1.4071 |
0.0000 |
-1.1612 |
|
0.0000 |
-1.4071 |
-1.1612 |
| H10 |
-1.9538 |
0.0000 |
0.5134 |
|
0.0000 |
-1.9538 |
0.5134 |
| H11 |
1.4071 |
0.0000 |
-1.1612 |
|
0.0000 |
1.4071 |
-1.1612 |
| H12 |
1.9538 |
0.0000 |
0.5134 |
|
0.0000 |
1.9538 |
0.5134 |
Atom - Atom Distances (Å)
| |
C1 |
C2 |
C3 |
C4 |
H5 |
H6 |
H7 |
H8 |
H9 |
H10 |
H11 |
H12 |
| C1 |
| 2.1569 |
1.5460 |
1.5460 |
1.0855 |
1.0843 |
2.6923 |
3.0990 |
2.1913 |
2.2649 |
2.1913 |
2.2649 |
| C2 |
2.1569 |
|
1.5460 |
1.5460 |
2.6923 |
3.0990 |
1.0855 |
1.0843 |
2.1913 |
2.2649 |
2.1913 |
2.2649 |
| C3 |
1.5460 |
1.5460 |
| 2.1569 |
2.1913 |
2.2649 |
2.1913 |
2.2649 |
1.0855 |
1.0843 |
2.6923 |
3.0990 |
| C4 |
1.5460 |
1.5460 |
2.1569 |
| 2.1913 |
2.2649 |
2.1913 |
2.2649 |
2.6923 |
3.0990 |
1.0855 |
1.0843 |
| H5 |
1.0855 |
2.6923 |
2.1913 |
2.1913 |
| 1.7616 |
2.8142 |
3.7550 |
3.0584 |
2.4934 |
3.0584 |
2.4934 |
| H6 |
1.0843 |
3.0990 |
2.2649 |
2.2649 |
1.7616 |
| 3.7550 |
3.9075 |
2.4934 |
2.9476 |
2.4934 |
2.9476 |
| H7 |
2.6923 |
1.0855 |
2.1913 |
2.1913 |
2.8142 |
3.7550 |
| 1.7616 |
3.0584 |
2.4934 |
3.0584 |
2.4934 |
| H8 |
3.0990 |
1.0843 |
2.2649 |
2.2649 |
3.7550 |
3.9075 |
1.7616 |
| 2.4934 |
2.9476 |
2.4934 |
2.9476 |
| H9 |
2.1913 |
2.1913 |
1.0855 |
2.6923 |
3.0584 |
2.4934 |
3.0584 |
2.4934 |
| 1.7616 |
2.8142 |
3.7550 |
| H10 |
2.2649 |
2.2649 |
1.0843 |
3.0990 |
2.4934 |
2.9476 |
2.4934 |
2.9476 |
1.7616 |
| 3.7550 |
3.9075 |
| H11 |
2.1913 |
2.1913 |
2.6923 |
1.0855 |
3.0584 |
2.4934 |
3.0584 |
2.4934 |
2.8142 |
3.7550 |
| 1.7616 |
| H12 |
2.2649 |
2.2649 |
3.0990 |
1.0843 |
2.4934 |
2.9476 |
2.4934 |
2.9476 |
3.7550 |
3.9075 |
1.7616 |
|
Maximum atom distance is 3.9075Å
between atoms H6 and H8.
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
| atom1 |
atom2 |
atom3 |
angle |
|
atom1 |
atom2 |
atom3 |
angle |
|
C1 |
C3 |
C2 |
88.462 |
|
C1 |
C4 |
C2 |
88.462 |
|
C3 |
C1 |
C4 |
88.462 |
|
C3 |
C2 |
C4 |
88.462 |
Calculated Bond Angles (degrees) (Involving Hydrogens)
| atom1 |
atom2 |
atom3 |
angle |
|
atom1 |
atom2 |
atom3 |
angle |
|
C1 |
C3 |
H9 |
111.551 |
|
C1 |
C3 |
H10 |
117.801 |
|
C1 |
C4 |
H11 |
111.551 |
|
C1 |
C4 |
H12 |
117.801 |
|
C2 |
C3 |
H9 |
111.551 |
|
C2 |
C3 |
H10 |
117.801 |
|
C2 |
C4 |
H11 |
111.551 |
|
C2 |
C4 |
H12 |
117.801 |
|
C3 |
C1 |
H5 |
111.551 |
|
C3 |
C1 |
H6 |
117.801 |
|
C3 |
C2 |
H7 |
111.551 |
|
C3 |
C2 |
H8 |
117.801 |
|
C4 |
C1 |
H5 |
111.551 |
|
C4 |
C1 |
H6 |
117.801 |
|
C4 |
C2 |
H7 |
111.551 |
|
C4 |
C2 |
H8 |
117.801 |
|
H5 |
C1 |
H6 |
108.549 |
|
H7 |
C2 |
H8 |
108.549 |
|
H9 |
C3 |
H10 |
108.549 |
|
H11 |
C4 |
H12 |
108.549 |
For information on specific bond angles or dihedrals
see the geometry comparison page in section
Comparisons > Geometry > Bonds, angles.