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Geometry for Si(CH3)4 (tetramethylsilane) 1A1 TD

1910171554
InChI=1S/C4H12Si/c1-5(2,3)4/h1-4H3 INChIKey=CZDYPVPMEAXLPK-UHFFFAOYSA-N

MP2=FULL/6-31G**


Point group is Td
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
Si1 0.0000 0.0000 0.0000   0.0000 0.0000 0.0000
C2 1.0875 1.0875 1.0875   1.0933 1.1002 1.0874
C3 -1.0875 -1.0875 1.0875   1.0817 -1.1002 -1.0874
C4 -1.0875 1.0875 -1.0875   -1.0930 -1.0747 1.0874
C5 1.0875 -1.0875 -1.0875   -1.0820 1.0747 -1.0874
H6 1.7297 0.4864 1.7297   1.7388 1.7354 0.4864
H7 1.7297 1.7297 0.4864   0.4956 1.7500 1.7296
H8 0.4864 1.7297 1.7297   1.7325 0.5066 1.7296
H9 -1.7297 -1.7297 0.4864   0.4771 -1.7500 -1.7296
H10 -0.4864 -1.7297 1.7297   1.7270 -0.5066 -1.7296
H11 -1.7297 -0.4864 1.7297   1.7207 -1.7354 -0.4864
H12 -1.7297 0.4864 -1.7297   -1.7387 -1.7240 0.4864
H13 -1.7297 1.7297 -0.4864   -0.4952 -1.7094 1.7296
H14 -0.4864 1.7297 -1.7297   -1.7320 -0.4661 1.7296
H15 1.7297 -1.7297 -0.4864   -0.4776 1.7094 -1.7296
H16 0.4864 -1.7297 -1.7297   -1.7274 0.4661 -1.7296
H17 1.7297 -0.4864 -1.7297   -1.7208 1.7240 -0.4864
Atom - Atom Distances (Å)
  Si1 C2 C3 C4 C5 H6 H7 H8 H9 H10 H11 H12 H13 H14 H15 H16 H17
Si1 1.8836 1.8836 1.8836 1.8836 2.4941 2.4941 2.4941 2.4941 2.4941 2.4941 2.4941 2.4941 2.4941 2.4941 2.4941 2.4941
C2 1.8836 3.0759 3.0759 3.0759 1.0892 1.0892 1.0892 4.0293 3.2903 3.2903 4.0293 3.2903 3.2903 3.2903 4.0293 3.2903
C3 1.8836 3.0759 3.0759 3.0759 3.2903 4.0293 3.2903 1.0892 1.0892 1.0892 3.2903 3.2903 4.0293 3.2903 3.2903 4.0293
C4 1.8836 3.0759 3.0759 3.0759 4.0293 3.2903 3.2903 3.2903 4.0293 3.2903 1.0892 1.0892 1.0892 4.0293 3.2903 3.2903
C5 1.8836 3.0759 3.0759 3.0759 3.2903 3.2903 4.0293 3.2903 3.2903 4.0293 3.2903 4.0293 3.2903 1.0892 1.0892 1.0892
H6 2.4941 1.0892 3.2903 4.0293 3.2903 1.7584 1.7584 4.2924 3.1341 3.5936 4.8924 4.2924 4.2924 3.1341 4.2924 3.5936
H7 2.4941 1.0892 4.0293 3.2903 3.2903 1.7584 1.7584 4.8924 4.2924 4.2924 4.2924 3.5936 3.1341 3.5936 4.2924 3.1341
H8 2.4941 1.0892 3.2903 3.2903 4.0293 1.7584 1.7584 4.2924 3.5936 3.1341 4.2924 3.1341 3.5936 4.2924 4.8924 4.2924
H9 2.4941 4.0293 1.0892 3.2903 3.2903 4.2924 4.8924 4.2924 1.7584 1.7584 3.1341 3.5936 4.2924 3.5936 3.1341 4.2924
H10 2.4941 3.2903 1.0892 4.0293 3.2903 3.1341 4.2924 3.5936 1.7584 1.7584 4.2924 4.2924 4.8924 3.1341 3.5936 4.2924
H11 2.4941 3.2903 1.0892 3.2903 4.0293 3.5936 4.2924 3.1341 1.7584 1.7584 3.5936 3.1341 4.2924 4.2924 4.2924 4.8924
H12 2.4941 4.0293 3.2903 1.0892 3.2903 4.8924 4.2924 4.2924 3.1341 4.2924 3.5936 1.7584 1.7584 4.2924 3.1341 3.5936
H13 2.4941 3.2903 3.2903 1.0892 4.0293 4.2924 3.5936 3.1341 3.5936 4.2924 3.1341 1.7584 1.7584 4.8924 4.2924 4.2924
H14 2.4941 3.2903 4.0293 1.0892 3.2903 4.2924 3.1341 3.5936 4.2924 4.8924 4.2924 1.7584 1.7584 4.2924 3.5936 3.1341
H15 2.4941 3.2903 3.2903 4.0293 1.0892 3.1341 3.5936 4.2924 3.5936 3.1341 4.2924 4.2924 4.8924 4.2924 1.7584 1.7584
H16 2.4941 4.0293 3.2903 3.2903 1.0892 4.2924 4.2924 4.8924 3.1341 3.5936 4.2924 3.1341 4.2924 3.5936 1.7584 1.7584
H17 2.4941 3.2903 4.0293 3.2903 1.0892 3.5936 3.1341 4.2924 4.2924 4.2924 4.8924 3.5936 4.2924 3.1341 1.7584 1.7584
Maximum atom distance is 4.8924Å between atoms H6 and H12.
picture of tetramethylsilane
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
C2 Si1 C3 109.471 C2 Si1 C4 109.471
C2 Si1 C5 109.471 C3 Si1 C4 109.471
C3 Si1 C5 109.471 C4 Si1 C5 109.471
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
Si1 C2 H6 111.238 Si1 C2 H7 111.238
Si1 C2 H8 111.238 Si1 C3 H9 111.238
Si1 C3 H10 111.238 Si1 C3 H11 111.238
Si1 C4 H12 111.238 Si1 C4 H13 111.238
Si1 C4 H14 111.238 Si1 C5 H15 111.238
Si1 C5 H16 111.238 Si1 C5 H17 111.238
H6 C2 H7 107.649 H6 C2 H8 107.649
H7 C2 H8 107.649 H9 C3 H10 107.649
H9 C3 H11 107.649 H10 C3 H11 107.649
H12 C4 H13 107.649 H12 C4 H14 107.649
H13 C4 H14 107.649 H15 C5 H16 107.649
H15 C5 H17 107.649 H16 C5 H17 107.649

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.