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Geometry for CH3NHNHCH3 (dimethyl hydrazine) 1A C2

1910171554
InChI=1S/C2H8N2/c1-3-4-2/h3-4H,1-2H3 INChIKey=DIIIISSCIXVANO-UHFFFAOYSA-N

B1B95/6-31G**


Point group is C2
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
N1 -0.1559 0.6886 -0.6808   -0.6747 -0.1803 0.6886
N2 0.1559 -0.6886 -0.6808   -0.6860 0.1313 -0.6886
C3 0.1559 1.4329 0.5269   0.5210 0.1748 1.4329
C4 -0.1559 -1.4329 0.5269   0.5322 -0.1368 -1.4329
H5 -1.1402 0.7726 -0.9069   -0.8653 -1.1721 0.7726
H6 1.1402 -0.7726 -0.9069   -0.9474 1.1068 -0.7726
H7 -0.1242 2.4764 0.3650   0.3693 -0.1110 2.4764
H8 -0.3430 1.0870 1.4449   1.4563 -0.2907 1.0870
H9 1.2359 1.4050 0.7008   0.6559 1.2604 1.4050
H10 0.1242 -2.4764 0.3650   0.3603 0.1373 -2.4764
H11 0.3430 -1.0870 1.4449   1.4316 0.3948 -1.0870
H12 -1.2359 -1.4050 0.7008   0.7449 -1.2099 -1.4050
Atom - Atom Distances (Å)
  N1 N2 C3 C4 H5 H6 H7 H8 H9 H10 H11 H12
N1 1.4121 1.4525 2.4412 1.0134 1.9663 2.0714 2.1708 2.0879 3.3451 2.8143 2.7310
N2 1.4121 2.4412 1.4525 1.9663 1.0134 3.3451 2.8143 2.7310 2.0714 2.1708 2.0879
C3 1.4525 2.4412 2.8827 2.0425 2.8088 1.0925 1.1006 1.0943 3.9128 2.6884 3.1656
C4 2.4412 1.4525 2.8827 2.8088 2.0425 3.9128 2.6884 3.1656 1.0925 1.1006 1.0943
H5 1.0134 1.9663 2.0425 2.8088 2.7546 2.3565 2.5031 2.9378 3.7112 3.3450 2.7085
H6 1.9663 1.0134 2.8088 2.0425 2.7546 3.7112 3.3450 2.7085 2.3565 2.5031 2.9378
H7 2.0714 3.3451 1.0925 3.9128 2.3565 3.7112 1.7732 1.7637 4.9590 3.7526 4.0514
H8 2.1708 2.8143 1.1006 2.6884 2.5031 3.3450 1.7732 1.7742 3.7526 2.2796 2.7497
H9 2.0879 2.7310 1.0943 3.1656 2.9378 2.7085 1.7637 1.7742 4.0514 2.7497 3.7425
H10 3.3451 2.0714 3.9128 1.0925 3.7112 2.3565 4.9590 3.7526 4.0514 1.7732 1.7637
H11 2.8143 2.1708 2.6884 1.1006 3.3450 2.5031 3.7526 2.2796 2.7497 1.7732 1.7742
H12 2.7310 2.0879 3.1656 1.0943 2.7085 2.9378 4.0514 2.7497 3.7425 1.7637 1.7742
Maximum atom distance is 4.9590Å between atoms H7 and H10.
picture of dimethyl hydrazine
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
N1 N2 C4 116.895 N2 N1 C3 116.895
Calculated Bond Angles (degrees) (Involving Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
N1 N2 H6 107.175 N1 C3 H7 108.130
N1 C3 H8 115.797 N1 C3 H9 109.325
N2 N1 H5 107.175 N2 C4 H10 108.130
N2 C4 H11 115.797 N2 C4 H12 109.325
C3 N1 H5 110.584 C4 N2 H6 110.584
H7 C3 H8 107.913 H7 C3 H9 107.517
H8 C3 H9 107.868 H10 C4 H11 107.913
H10 C4 H12 107.517 H11 C4 H12 107.868

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.