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Geometry for SF4 (Sulfur tetrafluoride) 1A1 C2V

1910171554
InChI=1S/F4S/c1-5(2,3)4 INChIKey=QHMQWEPBXSHHLH-UHFFFAOYSA-N

PBE1PBE/TZVP


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.3856   0.0000 0.0000 0.3856
F2 0.0000 1.6776 0.2769   1.6776 0.0000 0.2769
F3 0.0000 -1.6776 0.2769   -1.6776 0.0000 0.2769
F4 1.2216 0.0000 -0.6197   0.0000 1.2216 -0.6197
F5 -1.2216 0.0000 -0.6197   0.0000 -1.2216 -0.6197
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5
S1 1.6811 1.6811 1.5821 1.5821
F2 1.6811 3.3552 2.2606 2.2606
F3 1.6811 3.3552 2.2606 2.2606
F4 1.5821 2.2606 2.2606 2.4432
F5 1.5821 2.2606 2.2606 2.4432
Maximum atom distance is 3.3552Å between atoms F2 and F3.
picture of Sulfur tetrafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 172.581 F2 S1 F4 87.644
F2 S1 F5 87.644 F3 S1 F4 87.644
F3 S1 F5 87.644 F4 S1 F5 101.094

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.