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Geometry for SF4 (Sulfur tetrafluoride) 1A1 C2V

1910171554
InChI=1S/F4S/c1-5(2,3)4 INChIKey=QHMQWEPBXSHHLH-UHFFFAOYSA-N

MP2/TZVP


Point group is C2v
Atom Internal Principal
x (Å) y (Å) z (Å)   a (Å) b (Å) c (Å)
S1 0.0000 0.0000 0.3853   0.0000 0.0000 0.3853
F2 0.0000 1.6813 0.2759   1.6813 0.0000 0.2759
F3 0.0000 -1.6813 0.2759   -1.6813 0.0000 0.2759
F4 1.2214 0.0000 -0.6184   0.0000 1.2214 -0.6184
F5 -1.2214 0.0000 -0.6184   0.0000 -1.2214 -0.6184
Atom - Atom Distances (Å)
  S1 F2 F3 F4 F5
S1 1.6849 1.6849 1.5809 1.5809
F2 1.6849 3.3627 2.2624 2.2624
F3 1.6849 3.3627 2.2624 2.2624
F4 1.5809 2.2624 2.2624 2.4429
F5 1.5809 2.2624 2.2624 2.4429
Maximum atom distance is 3.3627Å between atoms F2 and F3.
picture of Sulfur tetrafluoride
Calculated Bond Angles (degrees) (Ignoring Hydrogens)
atom1 atom2 atom3 angle         atom1 atom2 atom3 angle
F2 S1 F3 172.551 F2 S1 F4 87.636
F2 S1 F5 87.636 F3 S1 F4 87.636
F3 S1 F5 87.636 F4 S1 F5 101.178

For information on specific bond angles or dihedrals see the geometry comparison page in section Comparisons > Geometry > Bonds, angles.